Voltammetric resolution of dopamine in the presence of ascorbic acid and uric acid at poly (calmagite) film coated carbon paste electrode

被引:136
作者
Chandra, Umesh [1 ]
Swamy, B. E. Kumara [1 ]
Gilbert, Ongera [1 ]
Sherigara, B. S. [1 ]
机构
[1] Kuvempu Univ, Dept P G Studies & Res Ind Chem, Shimoga 577451, Karnataka, India
关键词
Poly (calmagite); Carbon paste electrode; Dopamine; Ascorbic acid; Uric acid; Cyclic voltammetry; Differential pulse voltammetry; ELECTROCATALYTIC OXIDATION; ELECTROCHEMICAL POLYMERIZATION; EPINEPHRINE; NADH;
D O I
10.1016/j.electacta.2010.06.091
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The poly (calmagite) film was synthesized on the surface of carbon paste electrode by electrochemical method The synthesized polymer film coated electrode exhibits excellent electrocatalytic activity towards the detection of dopamine at neutral pH The scan rate effect was found to be adsorption controlled electrode process. The concentration effect of dopamine was studied The redox peak potentials of dopamine were depend on pH This polymer film coated electrode was very good at simultaneous study of dopamine in the presence of high concentrated ascorbic acid and uric acid. The incorporation study was clone by varying the concentration of one species while other two are kept constant The proposed method was applied to the detection of dopamine in injection samples. (C) 2010 Elsevier Ltd All rights reserved
引用
收藏
页码:7166 / 7174
页数:9
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