Properties of sugar, polyol, and polysaccharide water-ethanol solutions

被引:97
作者
Bouchard, Andreanne [1 ]
Hofland, Gerard W. [1 ]
Witkamp, Geert-Jan [1 ]
机构
[1] Delft Univ Technol, NL-2628 CA Delft, Netherlands
关键词
D O I
10.1021/je700190m
中图分类号
O414.1 [热力学];
学科分类号
摘要
The solubility and viscosity of sugars (glucose, lactose, leucrose, maltose, raffinose, sucrose, and trehalose), polyols (maltitol, mannitol, sorbitol, and xylitol), and polysaccharides (beta-cyclodextrin, dextrans, and inulin) in water and water-ethanol mixtures was investigated at 310 K. The increase in ethanol fraction caused a decrease in solubility in all cases. The viscosity of a 10 % (w/w) solution of any of those sugars was (1 to 1.25) mPa s except dextran solutions, which reached 5 mPa s. The viscosity of saturated solutions varied strongly from one compound to another even though the solubilities were similar. The metastable zone widths of sucrose, maltose, and lactose precipitated with ethanol were significantly larger than the one measured for mannitol.
引用
收藏
页码:1838 / 1842
页数:5
相关论文
共 41 条
[1]  
Bailey J.E., 2000, ULLMANNS ENCY IND CH
[2]  
Bates F.J., 1942, POLARIMETRY SACCHARI
[3]   Nucleation phenomena during the crystallisation and precipitation of Abecarnil [J].
Beckmann, W .
JOURNAL OF CRYSTAL GROWTH, 1999, 198 :1307-1314
[4]   SOLUBILITIES OF ALPHA-ANHYDROUS GLUCOSE IN ETHANOL WATER MIXTURES [J].
BOCKSTANZ, GL ;
BUFFA, M ;
LIRA, CT .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1989, 34 (04) :426-429
[5]  
Bubnik Z., 1995, Sucrose: properties and applications., P101
[6]   SALTING-OUT PRECIPITATION OF COCARBOXYLASE HYDROCHLORIDE FROM AQUEOUS-SOLUTION BY ADDITION OF ACETONE [J].
BUDZ, J ;
KARPINSKI, PH ;
MYDLARZ, J ;
NYVIT, J .
INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1986, 25 (04) :657-664
[7]  
Cakebread S. H., 1971, Confectionery Production, V37, P274
[8]   Apparent molar volume and viscosity studies on some carbohydrates in solutions [J].
Dey, PC ;
Motin, MA ;
Biswas, TK ;
Huque, EM .
MONATSHEFTE FUR CHEMIE, 2003, 134 (06) :797-809
[9]   THERMAL-EXPANSION AND SHEAR VISCOSITY COEFFICIENTS OF WATER + ETHANOL + SUCROSE MIXTURES [J].
DICKINSON, E ;
THRIFT, LJ ;
WILSON, L .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1980, 25 (03) :234-236
[10]   Production of sodium chloride crystals of uni-modal size distribution by batch dilution crystallization [J].
Doki, N ;
Kubota, N ;
Yokota, M ;
Kimura, S ;
Sasaki, S .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2002, 35 (11) :1099-1104