Photoionization Cross-Sections of Carbon-Like N+ Near the K-Edge (390-440 eV)

被引:3
作者
Mosnier, Jean-Paul [1 ]
Kennedy, Eugene T. [1 ]
Bizau, Jean-Marc [2 ,3 ]
Cubaynes, Denis [2 ,3 ]
Guilbaud, Segolene [2 ]
Blancard, Christophe [4 ,5 ]
McLaughlin, Brendan M. [6 ]
机构
[1] Dublin City Univ, Sch Phys Sci, Natl Ctr Plasma Sci & Technol NCPST, Dublin 9, Ireland
[2] Univ Paris Saclay, Inst Sci Mol Orsay, UMR 8214, Rue Andre Riviere,Batiment 520, F-91405 Orsay, France
[3] Synchrotron SOLEIL, Orme Merisiers, BP 48, F-91192 Gif Sur Yvette, France
[4] CEA, DAM, DIF, F-91297 Arpajon, France
[5] Univ Paris Saclay, Lab Matiere Condit Extremes, Commissariat Energie Atom & Energies Alternat, F-91680 Bruyeres Le Chatel, France
[6] Queens Univ Belfast, Sch Math & Phys, Ctr Theoret Atom Mol & Opt Phys CTAMOP, David Bates Bldg,7 Coll Pk, Belfast BT7 1NN, Antrim, North Ireland
关键词
atomic data; inner-shell photoionization; atomic nitrogen ion; X-RAY; SHELL PHOTOIONIZATION; SPECTROSCOPY; IONS;
D O I
10.3390/atoms9020027
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
High-resolution K-shell photoionization cross-sections for the C-like atomic nitrogen ion (N+) are reported in the 398 eV (31.15 angstrom) to 450 eV (27.55 angstrom) energy (wavelength) range. The results were obtained from absolute ion-yield measurements using the SOLEIL synchrotron radiation facility for spectral bandpasses of 65 meV or 250 meV. In the photon energy region 398-403 eV, 1s -> 2p autoionizing resonance states dominated the cross section spectrum. Analyses of the experimental profiles yielded resonance strengths and Auger widths. In the 415-440 eV photon region 1s ->(1s2s(2)2p(2 4)P)np and 1s ->(1s2s(2)2p(2) P-2)np resonances forming well-developed Rydberg series up n=7 and n=8 , respectively, were identified in both the single and double ionization spectra. Theoretical photoionization cross-section calculations, performed using the R-matrix plus pseudo-states (RMPS) method and the multiconfiguration Dirac-Fock (MCDF) approach were bench marked against these high-resolution experimental results. Comparison of the state-of-the-art theoretical work with the experimental studies allowed the identification of new resonance features. Resonance strengths, energies and Auger widths (where available) are compared quantitatively with the theoretical values. Contributions from excited metastable states of the N+ ions were carefully considered throughout.
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页数:18
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