Stereoselective Reactions with Chiral Schiff Base Metal Complexes

被引:13
作者
Gualandi, Andrea [1 ]
Wilson, Claire Margaret [2 ]
Cozzi, Pier Giorgio [1 ]
机构
[1] ALMA MATER STUDIORUM Univ Bologna, Dipartimento Chim G Ciamician, Via Selmi 2, I-40126 Bologna, Italy
[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
关键词
Catalysis; Lewis acids; Metal Complexes; Schiff Bases; Stereocontrol; REFORMATSKY-TYPE REACTION; ENANTIOSELECTIVE CATALYTIC ADDITION; BETA-AMINO ESTERS; ASYMMETRIC CATALYSIS; KINETIC RESOLUTION; PHOTOREDOX CATALYSIS; CR(SALEN) COMPLEXES; ALDEHYDES; SALEN; EPOXIDES;
D O I
10.2533/chimia.2017.562
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chiral Schiff bases are privileged chiral ligands, capable of transmitting chiral information in many stereoselective processes. Their modular nature, the possibility to modify their electronic character, and their ability to coordinate many metals, gives these chiral ligands broad utility and these have been investigated by many research groups around the world. For more than 20 years our research group has devoted attention to the application of chiral Schiff bases in the development of new stereoselective processes and in this brief survey we present our principal results and achievements in this field.
引用
收藏
页码:562 / 567
页数:6
相关论文
共 76 条
[1]   Multiple component reactions:: An efficient nickel-catalyzed reformatsky-type reaction and its application in the parallel synthesis of β-amino carbonyl libraries [J].
Adrian, JC ;
Snapper, ML .
JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (06) :2143-2150
[2]  
Adrian JC, 2000, J ORG CHEM, V65, P6264
[3]  
[Anonymous], 2010, CATALYTIC ASYMMETRIC
[4]  
Aufustin D., 2000, ORGANOMETALLICS, V19, P4276
[5]   Chiral salen complexes: An overview to recoverable and reusable homogeneous and heterogeneous catalysts [J].
Baleizao, Carlos ;
Garcia, Hermenegildo .
CHEMICAL REVIEWS, 2006, 106 (09) :3987-4043
[6]   Light: A Very Peculiar Reactant and Product [J].
Balzani, Vincenzo ;
Bergamini, Giacomo ;
Ceroni, Paola .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (39) :11320-11337
[7]  
Bandini M, 1999, ANGEW CHEM INT EDIT, V38, P3357, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3357::AID-ANIE3357>3.0.CO
[8]  
2-W
[9]   Kinetic resolution of epoxides by a C-C bond-forming reaction:: Highly enantioselective addition of indoles to cis, trans, and meso aromatic epoxides catalyzed by [Cr(salen)] complexes [J].
Bandini, M ;
Cozzi, PG ;
Melchiorre, P ;
Umani-Ronchi, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (01) :84-87
[10]   Cr(Salen)-catalyzed addition of 1,3-dichloropropene to aromatic aldehydes, a simple access to optically active vinyl epoxides [J].
Bandini, M ;
Cozzi, PG ;
Melchiorre, P ;
Morganti, S ;
Umani-Ronchi, A .
ORGANIC LETTERS, 2001, 3 (08) :1153-1155