Construction of a tube-like molecule via sequential cyclopropylidene dimerisation and intramolecular [pi 2s+pi 2s] cycloaddition reactions

被引：11

作者：

Banwell, MG ^{[1
]}

Hockless, DCR ^{[1
]}

Walter, JM ^{[1
]}

机构：

[1] UNIV MELBOURNE,SCH CHEM,PARKVILLE,VIC 3052,AUSTRALIA

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 12期

关键词：

D O I：

10.1039/cc9960001469

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syn-cyclopropylidene dimer 5, obtained by reaction of compound 4 with methyllithium, is readily elaborated to the bis-p-benzoquinone 7 which undergoes intramolecular [pi 2s+pi 2s] cycloaddition to give the tube-like molecule 8.

引用

页码：1469 / 1470

页数：2

共 23 条

[11] NANOSCALE TUBULAR ENSEMBLES WITH SPECIFIED INTERNAL DIAMETERS - DESIGN OF A SELF-ASSEMBLED NANOTUBE WITH A 13-ANGSTROM PORE
KHAZANOVICH, N
GRANJA, JR
MCREE, DE
MILLIGAN, RA
GHADIRI, MR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (13) : 6011 - 6012
[12] MARQUIS ET, 1966, J CHEM SOC CHEM COMM, P726
[13] SECOHEXAPRISMANE
MEHTA, G
PADMA, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (07) : 2212 - 2213
[14] MEHTA G, 1992, CARBOCYCLIC CAGE COM, P183
[15] *MOL STRUCT CORP, 1995, TEXSAN SINGL CRYST S
[16] MOLCHANOV AP, 1992, ZH ORG KHIM, V28, P102
[17] REACTIONS OF GEM-DIBROMOCYCLOPROPANES WITH ALKYLLITHIUM REAGENTS - FORMATION OF ALLENES, SPIROPENTANES, AND A DERIVATIVE OF BICYCLOPROPYLIDENE
MOORE, WR
WARD, HR
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1960, 25 (11) : 2073 - 2073
[18] FORMATION OF OPTICALLY ACTIVE 1,2-CYCLONONADIENE FROM 2 DIFFERENT CYCLOPROPYLIDENE PRECURSORS
MOORE, WR
BACH, RD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (09) : 3148 - &
[19] SYNTHESIS OF BIS(NORCARA-2,4,2',4'-TETRAENYLIDES ON A CARBENE DIMERIZATION
PILIDIS, G
[J]. COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1986, 51 (10) : 2151 - 2157
[20] CHEMISTRY OF GEM-DIHALOCYCLOPROPANES .23. REACTION OF SOME GEM-DIBROMOCYCLOPROPYL ACETALS WITH METHYLLITHIUM
SKATTEBOL, L
STENSTROM, Y
STJERNA, MB
[J]. ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1988, 42 (07): : 475 - 483

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