Efficient vapor-assisted aging synthesis of functional and highly crystalline MOFs from CuO and rare earth sesquioxides/carbonates

被引：36

作者：

Feng, Xiao ^{[1
]}

Jia, Chunmei ^{[1
]}

Wang, Jing ^{[1
]}

Cao, Xiaocong ^{[1
]}

Tang, Panjuan ^{[1
]}

Yuan, Wenbing ^{[1
]}

机构：

[1] Hainan Univ, Sch Mat & Chem Engn, Minist Educ, Lab Trop Biol Resources, Haikou 570228, Peoples R China

来源：

GREEN CHEMISTRY | 2015年 / 17卷 / 07期

关键词：

METAL-ORGANIC FRAMEWORKS; HYDROGEN ADSORPTION; SORPTION PROPERTIES; CU-3(BTC)(2); SEPARATION; OXIDE; BTC;

D O I：

10.1039/c5gc00378d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four functional MOFs including HKUST-1 were prepared quantitatively from CuO and rare earth sesquioxides/carbonates under vapour-assisted aging at room temperature within hours or days. Two 1-D complexes show high reactivity under VAG to be transformed into two 3-D compounds within hours.

引用

页码：3740 / 3745

页数：6

共 38 条

[1] The binary rare earth oxides [J].

Adachi, G ;

Imanaka, N .

CHEMICAL REVIEWS, 1998, 98 (04) :1479-1514

[2] Probing the Lewis acidity and catalytic activity of the metal-organic framework [Cu3(btc)2] (BTC = benzene-1,3,5-tricarboxylate) [J].

Alaerts, Luc ;

Seguin, Etienne ;

Poelman, Hilde ;

Thibault-Starzyk, Frederic ;

Jacobs, Pierre A. ;

De Vos, Dirk E. .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (28) :7353-7363

[3] Rapid Room-Temperature Synthesis of Zeolitic Imidazolate Frameworks by Using Mechanochemistry [J].

Beldon, Patrick J. ;

Fabian, Laszlo ;

Stein, Robin S. ;

Thirumurugan, A. ;

Cheetham, Anthony K. ;

Friscic, Tomislav .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (50) :9640-9643

[4] BEHAVIOR OF RARE-EARTH SESQUIOXIDES EXPOSED TO ATMOSPHERIC CARBON-DIOXIDE AND WATER [J].

BERNAL, S ;

BOTANA, FJ ;

GARCIA, R ;

RODRIGUEZIZQUIERDO, JM .

REACTIVITY OF SOLIDS, 1987, 4 (1-2) :23-40

[5] Oriented growth of the metal organic framework Cu3(BTC)2(H2O)3•xH2O tunable with functionalized self-assembled monolayers [J].

Biemmi, Enrica ;

Scherb, Camilla ;

Bein, Thomas .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (26) :8054-+

[6] AMMINEITE, CuCl2(NH3)2, A NEW SPECIES CONTAINING AN AMMINE COMPLEX: MINERAL DATA AND CRYSTAL STRUCTURE [J].

Bojar, Hans-Peter ;

Walter, Franz ;

Baumgartner, Judith ;

Faerber, Gunnar .

CANADIAN MINERALOGIST, 2010, 48 (06) :1359-1371

[7] Solvent effect in a "solvent free" reaction [J].

Braga, Dario ;

Giaffreda, Stefano Luca ;

Grepioni, Fabrizia ;

Chierotti, Michele R. ;

Gobetto, Roberto ;

Palladino, Giuseppe ;

Polito, Marco .

CRYSTENGCOMM, 2007, 9 (10) :879-881

[8] From unexpected reactions to a new family of ionic co-crystals: the case of barbituric acid with alkali bromides and caesium iodide [J].

Braga, Dario ;

Grepioni, Fabrizia ;

Maini, Lucia ;

Prosperi, Susanna ;

Gobetto, Roberto ;

Chierotti, Michele R. .

CHEMICAL COMMUNICATIONS, 2010, 46 (41) :7715-7717

[9] Self-assembled four-membered networks of trimesic acid forming organic channel structures [J].

Chatterjee, S ;

Pedireddi, VR ;

Ranganathan, A ;

Rao, CNR .

JOURNAL OF MOLECULAR STRUCTURE, 2000, 520 :107-115

[10] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].

Chui, SSY ;

Lo, SMF ;

Charmant, JPH ;

Orpen, AG ;

Williams, ID .

SCIENCE, 1999, 283 (5405) :1148-1150

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