Near- and mid-infrared spectroscopy study of synthetic hydrocalumites

被引:21
作者
Mora, Manuel [1 ]
Isabel Lopez, Maria [1 ]
Jimenez-Sanchidrian, Cesar [1 ]
Rafael Ruiz, Jose [1 ]
机构
[1] Univ Cordoba, Dept Quim Organ, Cordoba 14014, Spain
关键词
NIR spectroscopy; Hydrocalumite; Layered double hydroxides; NEAR-INFRARED SPECTROSCOPY; LAYERED DOUBLE HYDROXIDES; CATALYSTS;
D O I
10.1016/j.solidstatesciences.2010.10.017
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Three hydrocalumites containing Ca and Al in a 3:1 ratio, and carbonate as interlayer anion, were synthesized by coprecipitation, homogeneous precipitation in the presence of urea and the sol gel method. The three solids thus obtained were for the first time characterized by using near- and mid-infrared spectroscopies. The structural similarity of the solids determined by X-ray diffraction was confirmed by the spectroscopic results. (C) 2010 Elsevier Masson SAS. All rights reserved.
引用
收藏
页码:101 / 105
页数:5
相关论文
共 32 条
[1]   Comparative study of Mg Al and Mg Ga layered double hydroxides [J].
Aramendía, MA ;
Avilés, Y ;
Benítez, JA ;
Borau, V ;
Jiménez, C ;
Marinas, JM ;
Ruiz, JR ;
Urbano, FJ .
MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 29 (03) :319-328
[2]   Synthesis and thermal evolution of hydrotalcite-type compounds containing noble metals [J].
Basile, F ;
Fornasari, G ;
Gazzano, M ;
Vaccari, A .
APPLIED CLAY SCIENCE, 2000, 16 (3-4) :185-200
[3]   HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS [J].
Cavani, F. ;
Trifiro, F. ;
Vaccari, A. .
CATALYSIS TODAY, 1991, 11 (02) :173-301
[4]  
Czarnik-Matusewicz B, 2000, J PHYS ORG CHEM, V13, P237, DOI 10.1002/1099-1395(200005)13:5<237::AID-POC236>3.0.CO
[5]  
2-9
[6]   Exploring, Tuning, and Exploiting the Basicity of Hydrotalcites for Applications in Heterogeneous Catalysis [J].
Debecker, Damien P. ;
Gaigneaux, Eric M. ;
Busca, Guido .
CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (16) :3920-3935
[7]  
Forano C, 2006, DEV CLAY SCI, V1, P1021, DOI 10.1016/S1572-4352(05)01039-1
[8]   Near-infrared and mid-IR spectroscopy of selected humite minerals [J].
Frost, Ray L. ;
Palmer, Sara J. ;
Reddy, B. Jagannadha .
VIBRATIONAL SPECTROSCOPY, 2007, 44 (01) :154-161
[9]   Mid-infrared and near-infrared spectroscopic study of selected magnesium carbonate minerals containing ferric iron-Implications for the geosequestration of greenhouse gases [J].
Frost, Ray L. ;
Reddy, B. Jagannadha ;
Bahfenne, Silmarilly ;
Graham, Jessica .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2009, 72 (03) :597-604
[10]   Infrared and near-infrared spectroscopic study of synthetic hydrotalcites with variable divalent/trivalent cationic ratios [J].
Frost, Ray L. ;
Spratt, Henry J. ;
Palmer, Sara J. .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2009, 72 (05) :984-988