A total synthesis of (+)-Goniodiol using an anomeric oxygen-to-carbon rearrangement

被引：38

作者：

Dixon, DJ ^{[1
]}

Ley, SV ^{[1
]}

Tate, EW ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 19期

关键词：

D O I：

10.1039/a806584e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new route to (+)-Goniodiol 1, a potent and selective cytotoxin, is described, using a diastereoselective oxygen-to-carbon rearrangement of an anomerically linked silyl enol ether as the key step.

引用

页码：3125 / 3126

页数：2

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