Di-μ-phenylselenolato-bis[chloro(triphenylphosphine)palladium(II)]

被引：3
作者：
Hannu-Kuure, MS
Oilunkaniemi, R
Laitinen, RS
Ahlgren, M
机构：
[1] Univ Oulu, Dept Chem, FIN-90014 Oulu, Finland
[2] Univ Joensuu, Dept Chem, FIN-80101 Joensuu, Finland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536804000960
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Pd2Cl2(mu-C6H5Se)(2)(C18H15P)(2)], crystallizes as a centrosymmetric phenylselenolato-bridged dinuclear palladium complex. The Pd atom shows a slightly distorted square-planar coordination geometry, with the Pd-Se distance trans to the terminal Cl- ligand at 2.4174 (6) Angstrom and that trans to the triphenyl phospine at 2.4748 (7) Angstrom. These values are consistent with the relative trans influence of Cl- and PPh3. The terminal Cl- ligands are in trans positions with respect to each other.
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收藏
页码：M214 / M216
页数：3
相关论文
共 14 条
[1]   Mononuclear palladium(II) complexes with the phenylselenolato ligand.: The crystal and molecular structure of trans-[Pd(SePh)2(P(n-Bu)3)2]. [J].
Alyea, EC ;
Ferguson, G ;
Kannan, S .
POLYHEDRON, 1998, 17 (13-14) :2231-2235
[2]  
BRANDENBURG K, 1999, DIAMOND RELEASE 2 1
[3]  
*BRUK AXS INC, 2001, SHELXTL VERS 6 12
[4]  
Farrugia L. J., 1999, J. Appl. Crystallogr, V32, P837, DOI DOI 10.1107/S0021889899006020
[5]   Isomerism in bis(phenylselenolato) bis(triphenylphosphine) platinum(II):: the crystal and molecular structures of cis- and trans-[Pt(SePh)2(PPh3)2] [J].
Hannu, MS ;
Oilunkaniemi, R ;
Laitinen, RS ;
Ahlgén, M .
INORGANIC CHEMISTRY COMMUNICATIONS, 2000, 3 (07) :397-399
[6]   Formation and structural characterization of novel polynuclear palladium selenolato complexes [Pd3Se(SePh)3(PPh3)3]Cl and [Pd6Cl2Se4(SePh)2(PPh3)6] [J].
Hannu-Kuure, MS ;
Palda'n, K ;
Oilunkaniemi, R ;
Laitinen, RS ;
Ahlgrén, M .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 687 (02) :538-544
[7]   An experimental and theoretical study of the isomerization of mononuclear bis(arylselenolato)bis(triphenylphosphine)platinum complexes [Pt(SeR)2(PPh3)2] [J].
Hannu-Kuure, MS ;
Komulainen, J ;
Oilunkaniemi, R ;
Laitinen, RS ;
Suontamo, R ;
Ahlgrén, M .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 666 (1-2) :111-120
[8]  
Nonius, 1998, COLLECT
[9]   C4H3SSeCH2CH2OC6H5:: synthesis, characterization and reaction with palladium(II) and nickel(II) [J].
Oilunkaniemi, R ;
Laitinen, RS ;
Hannu-Kuure, MS ;
Ahlgrén, M .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 678 (1-2) :95-101
[10]   The NMR spectroscopic and X-ray crystallographic study of the oxidative addition of bis(2-thienyl) diselenide to zerovalent palladium and platinum centers [J].
Oilunkaniemi, R ;
Laitinen, RS ;
Ahlgrán, M .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 587 (02) :200-206
12