Advances and limits in copolymerization of olefins with conjugated dienes

被引:20
作者
Boisson, C
Monteil, V
Thuilliez, J
Spitz, R
Monnet, C
Llauro, MF
Barbotin, F
Robert, P
机构
[1] CNRS, ESCPE, Lab Chim & Procedes Polymerisat, Villeurbanne, France
[2] CNRS, FR2151, Serv RMN Federat Polymeristes Lyonnais, F-69390 Vernaison, France
[3] Manufacture Francaise Pneumat Michelin, F-63040 Clermont Ferrand, France
关键词
copolymerization; metallocene; neodymium; poly(ethylene-co-butadiene);
D O I
10.1002/masy.200550802
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The field of the copolymerization of olefins with conjugated dienes has been investigated. While the insertion of butadiene is often limited with most catalyst systems designed for olefin polymerization, lanthanide metallocene catalysts insert butadiene with good efficiency. In the present paper, the preparation of a vast range of products including new polymers is reviewed.
引用
收藏
页码:17 / 23
页数:7
相关论文
共 17 条
[1]   First synthesis of poly(ethene-co-1,3-butadiene) with neodymocene catalysts [J].
Barbotin, F ;
Monteil, V ;
Llauro, MF ;
Boisson, C ;
Spitz, R .
MACROMOLECULES, 2000, 33 (23) :8521-8523
[2]   Lanthanidocene catalysts for the homo- and copolymerization of ethylene with butadiene [J].
Boisson, C ;
Monteil, V ;
Ribour, D ;
Spitz, R ;
Barbotin, F .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2003, 204 (14) :1747-1754
[3]   The dual-site alternating cyclocopolymerization of 1,3-butadiene with ethylene [J].
Choo, TN ;
Waymouth, RM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (30) :8970-8971
[4]   ALTERNATING CO-POLYMERIZATION [J].
FURUKAWA, J ;
KOBAYASHI, E .
RUBBER CHEMISTRY AND TECHNOLOGY, 1978, 51 (03) :600-646
[5]  
GALIMBERTI M, 1991, MAKROMOL CHEM, V192, P2591
[6]   ELASTOMERS BY ATACTIC LINKAGE OF ALPHA-OLEFINS USING SOLUBLE ZIEGLER CATALYSTS [J].
KAMINSKY, W ;
SCHLOBOHM, M .
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1986, 4 :103-118
[7]   Investigation of ethylene/butadiene copolymers microstructure by 1H and 13C NMR [J].
Llauro, MF ;
Monnet, C ;
Barbotin, F ;
Monteil, V ;
Spitz, R ;
Boisson, C .
MACROMOLECULES, 2001, 34 (18) :6304-6311
[8]  
MITSUI CHEM, 1999, Patent No. 891993
[9]   Evidence of intramolecular cyclization in copolymerization of ethylene with 1,3-butadiene: Thermal properties of the resulting copolymers [J].
Monteil, V ;
Spitz, R ;
Barbotin, F ;
Boisson, C .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2004, 205 (06) :737-742
[10]  
NATTA G, 1964, MAKROMOLEKUL CHEM, V79, P161