UV-visible and infrared absorption spectroscopic studies of gamma irradiated tungsten-doped lithium phosphate glasses

被引:14
作者
ElBatal, F. H. [1 ]
Ouis, M. A. [1 ]
机构
[1] Natl Res Ctr, Glass Res Dept, Cairo, Egypt
关键词
Lithium phosphate glass; Tungsten; UV-visible; IR spectra; Gamma rays; SODIUM-PHOSPHATE; RADIATION DEFECTS; SILICATE-GLASSES; BORATE GLASSES; LEAD PHOSPHATE; SPECTRA; RAMAN; SYSTEM; IONS; CONDUCTIVITY;
D O I
10.1016/j.physb.2011.07.035
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Ultraviolet-visible and infrared spectroscopic techniques were employed to investigate the undoped lithium phosphate glass and other samples of the same composition doped with varying WO3 contents. The same spectroscopic properties were remeasured after subjecting the samples to 3 and 6 Mrad doses of gamma irradiation on the measured properties. Such combined analytical techniques are expected to give information about the state of tungsten ions in such lithium phosphate glass and justify the effect of gamma irradiation. The work aims to deduce the radiation-induced defects generated through successive gamma irradiation by optical measurements. Also, the study is expected to realize through IR spectroscopy, the main structural building groups and the influence of tungsten ions within the structural vibrational groups of the studied glasses. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:4175 / 4182
页数:8
相关论文
共 67 条
  • [11] Effect of CuO on the structure and properties of (50-x/2)Na2O-xCuO-(50-x/2)P2O5 glasses
    Chahine, A
    Et-tabirou, M
    Elbenaissi, M
    Haddad, M
    Pascal, JL
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2004, 84 (2-3) : 341 - 347
  • [12] CHO YI, 2004, SOLID STATE IONICS, V175, P687
  • [13] INTEGRAL ANTIREFLECTIVE SURFACE PRODUCTION ON OPTICAL-GLASS
    COOK, LM
    CIOLEK, S
    MADER, KH
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1982, 65 (09) : C152 - C155
  • [14] Cotton A. F., 1999, ADV INORG CHEM, V6th
  • [15] Dimitriev Y., 1992, P 16 INT C GLASS, V3, P293
  • [16] Basicity variation in network oxides: Distribution of metal ion sites in borate glass systems
    Duffy, JA
    Harris, B
    Kamitsos, EI
    Chryssikos, GD
    Yiannopoulos, YD
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (21): : 4188 - 4192
  • [17] USE OF THALLIUM(I), LEAD(II), AND BISMUTH(III) AS SPECTROSCOPIC PROBES FOR IONIC-COVALENT INTERACTION IN GLASSES
    DUFFY, JA
    INGRAM, MD
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1970, 52 (07) : 3752 - &
  • [18] DUFFY JA, 1974, PHYS CHEM GLASSES, V15, P34
  • [19] DUFFY JA, 1972, PHYS CHEM GLASSES, V13, P65
  • [20] UV-vis absorption of the transition metal-doped SiO2-B2O3-Na2O glasses
    Efflatal, F. H.
    Selim, M. S.
    Marzouk, S. Y.
    Azooz, M. A.
    [J]. PHYSICA B-CONDENSED MATTER, 2007, 398 (01) : 126 - 134