Cobalt(III)-mediated disulfuration and hydrosulfuration of alkynes

被引：24

作者：

Xu, Bao-Hua ^{[1
]}

Peng, Xu-Qing ^{[1
]}

Xu, Zhi-Wei ^{[1
]}

Li, Yi-Zhi ^{[1
]}

Yan, Hong ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Joint Lab Met Chem,Nanjing Univ Jin Chuan Grp Ltd, Jiangsu 210093, Peoples R China

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 17期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1021/ic801199e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Disulfuration and hydrosulfuration of alkynes mediated by an unusual square-planar tetrathiolate cobalt(III) complex [CP2Co](+)[Co(S2C2B10H10)(2)](-), 1, lead to a series of cobalt-free carboranyl vinyl sulfides 2-9. All new complexes 1, 2, 3, 4, 5, 6, 7, 8, and 9 were characterized by NMR spectroscopy (H-1, B-11, C-13), and X-ray structural analyses were performed for 1, 2, 3, 5, 6, 7, and 9.

引用

页码：7928 / 7933

页数：6

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