Base catalyzed sustainable synthesis of phenyl esters from carboxylic acids using diphenyl carbonate

被引：14
|
作者：
Kreye, Oliver [1 ]
Meier, Michael A. R. [1 ]
机构：
[1] Karlsruhe Inst Technol, Inst Organ Chem, Lab Appl Chem, D-76131 Karlsruhe, Germany
来源：
RSC ADVANCES | 2015年 / 5卷 / 65期
关键词：
PHOTO-FRIES REARRANGEMENT; SOLID-STATE POLYMERIZATION; PHOSGENE-FREE SYNTHESIS; DIMETHYL CARBONATE; BISPHENOL-A; MELT TRANSESTERIFICATION; OXIDATIVE CARBONYLATION; AMINO-ACIDS; TRANS-ESTERIFICATION; BENZOIC-ACIDS;
D O I：
10.1039/c5ra10206e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Phenyl esters were obtained in moderate to high yields by reaction of aliphatic and aromatic carboxylic acids with one equivalent of diphenyl carbonate in the presence of catalytic amounts of tertiary amine bases, such as DBU, TBD and DMAP under neat conditions at elevated temperatures (>100 degrees C).
引用
收藏
页码：53155 / 53160
页数：6
相关论文
共 50 条
12345