New spirostanol saponins from Chinese chives (Allium tuberosum)

被引：22
|
作者：
Sang, SM
Zou, ML
Xia, ZH
Lao, AA [1 ]
Chen, ZL
Ho, CT
机构：
[1] Chinese Acad Sci, Shanghai Inst Biol Sci, Inst Mat Med, Shanghai 200031, Peoples R China
[2] Rutgers State Univ, Dept Food Sci, New Brunswick, NJ 08901 USA
来源：
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 2001年 / 49卷 / 10期
关键词：
Allium tuberosum; Liliaceae; spirostanol saponins; tuberosides J; K; and L;
D O I：
10.1021/jf010529v
中图分类号：
S [农业科学];
学科分类号：
09 ;
摘要：
Three new spirostanol saponins have been isolated from the seeds of Allium tuberosum. On the basis of acid hydrolysis and comprehensive spectroscopic analysis, their structures were established as tuberoside J, (25R)-5 alpha -spirostan-2 alpha ,3 beta ,27-triol 3-O-alpha -L-rhamnopyranosyl-(1 -->2)-beta -D-glucopyranoside; tuberoside K, (25R)-5 alpha -spirostan-2 alpha ,3 beta ,27-triol 3-O-alpha -L-rhamnopyranosyl-(1 -->2)-[alpha -L-rhamnopyranosyl-(1 -->4)]-beta -D-glucopyranoside; and tuberoside L, 27-O-beta -D-glucopyranosyl-(25R)-5 alpha -spirostan-2 alpha ,3 beta ,27-triol 3-O-alpha -D-rhamnopyranosyl-(1 -->2)-[alpha -L-rhamnopyranosyl-(1 -->4)]-beta -D-glucopyranoside.
引用
收藏
页码：4780 / 4783
页数：4
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