Heterogeneous catalysis of the glycerol hydrogenolysis

被引：365

作者：

Nakagawa, Yoshinao ^{[1
]}

Tomishige, Keiichi ^{[1
]}

机构：

[1] Tohoku Univ, Sch Engn, Dept Appl Chem, Aoba Ku, Sendai, Miyagi 9808579, Japan

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2011年 / 1卷 / 02期

关键词：

PRECIPITATION-GEL METHOD; ION-EXCHANGE-RESIN; SELECTIVE HYDROGENOLYSIS; PROPYLENE-GLYCOL; 1,2-PROPANEDIOL; CONVERSION; ACID; RUTHENIUM; 1,3-PROPANEDIOL; DEOXYGENATION;

D O I：

10.1039/c0cy00054j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Glycerol has become an important feedstock for chemicals. Selective hydrogenolysis of glycerol has been attempted using several types of catalysts: non-noble-metal catalysts, noble-metal catalysts with an acid as an additive, noble-metal catalysts combined with a base, and metal-oxide-modified noble-metal catalysts. The former three approaches give 1,2-propanediol as a main product, while the mechanisms may be different. Only the last one can selectively give the more valuable 1,3-propanediol.

引用

页码：179 / 190

页数：12

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