Preparation of magnetically recyclable CuFe2O4/RGO for catalytic hydrolysis of sodium borohydride

CuFe2O4/reduced graphene oxide (RGO) nanostructures were fabricated by a facile chemical method, and the shape and size of the CuFe2O4 nanoparticles were tuned through changing the concentration of the reactants and the reaction temperature. The CuFe2O4/RGO nanostructures were firstly analyzed by transmission electron microscopy, Fourier Transform infrared spectroscopy and powder X-ray diffraction, and then they were exploited as magnetically recyclable catalyst for the hydrolytic dehydrogenation of NaBH4 for hydrogen evolution. They exhibited superior catalytic activity and recyclability. The calculated activation energy was 33.95 kJ mol(-1), which is even lower than some metallic nanoparticle catalysts. So the CuFe2O4/RGO nanostructures will find potential applications as magnetically recyclable catalysts in hydrogen storage system for fuel cell applications. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.