(Ba, Ca)(Ti, Zr)O3-BiFeO3 lead-free piezoelectric ceramics

被引:54
作者
Wu, Jiagang [1 ]
Wu, Wenjuan [1 ]
Xiao, Dingquan [1 ]
Wang, John [2 ]
Yang, Zhenchun [2 ]
Peng, Zhihang [1 ]
Chen, Qiang [1 ]
Zhu, Jianguo [1 ]
机构
[1] Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China
[2] Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 117574, Singapore
基金
美国国家科学基金会;
关键词
Lead-free piezoelectric ceramic; BiFeO3; Microstructure; Electrical properties; BARIUM-TITANATE CERAMICS; DIELECTRIC-PROPERTIES; FREE PIEZOCERAMICS; D(33) COEFFICIENT; TEMPERATURE; CONSTANTS;
D O I
10.1016/j.cap.2011.08.016
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Effects of BiFeO3 (BFO) content on the microstructure and electrical properties of Ba0.85Ca0.15Ti0.90Zr0.10O3 (BCTZ) ceramics prepared by normal sintering in air were investigated. A stable solid solution is formed between BCTZ and BFO. The grain size gradually becomes smaller, and the ceramics become denser with increasing the BFO content. The Curie temperature, dielectric constant, and dielectric loss of BCTZ ceramics decrease simultaneously with the introduction of BFO. Moreover, the remanent polarization reaches a maximum at x = 0.2 mol%, and the coercive field continuously increases with increasing the BFO content due to the introduction of BFO with a higher coercive field. Improved piezoelectric properties (d(33) similar to 405 pC/N and k(p) similar to 0.44) are demonstrated for the BCTZ ceramic with x = 0.2 mol%. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:534 / 538
页数:5
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