Total synthesis of preswinholide A .1. Stereoselective synthesis of the C11-C23 segment

被引：21
作者：
Nagasawa, K
Shimizu, I
Nakata, T
机构：
[1] INST PHYS & CHEM RES,WAKO,SAITAMA 35101,JAPAN
[2] WASEDA UNIV,SCH SCI & ENGN,DEPT APPL CHEM,SHINJUKU KU,TOKYO 169,JAPAN
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 38期
关键词：
D O I：
10.1016/0040-4039(96)01503-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The C11-C23 segment of preswinholide A was stereoselectively synthesized based on the iterative construction of 1,3-polyol chains using a series of sequential reactions which involves the Sharpless asymmetric epoxidation of allyl alcohol and Pd-catalyzed hydrogenolysis of alkenyl oxirane with HCOOH as the key reactions. Copyright (C) 1996 Elsevier Science Ltd
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页码：6881 / 6884
页数：4
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