Electrochemical attachment of organic groups to carbon felt surfaces

被引:81
作者
Coulon, E
Pinson, J [1 ]
Bourzat, JD
Commerçon, A
Pulicani, JP
机构
[1] Univ Paris 07, Electrochim Mol Lab, F-75251 Paris 05, France
[2] Aventis Pharma, Ctr Rech Vitry, F-94403 Vitry Sur Seine, France
关键词
D O I
10.1021/la010486c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrochemical reduction of diazonium salts and oxidation of carboxylates on high surface felt electrodes permits functionalization of the surface of the felt. The functionalization has been ascertained by different methods including elemental analysis, X-ray photoelectron spectroscopy, scanning microscopy/energy-dispersive spectrometry, and IR spectroscopy. The loadings which are obtained are of the same order of magnitude as those of commercial ion-exchange resins or of resins used for combinatorial chemistry.
引用
收藏
页码:7102 / 7106
页数:5
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