Oxide Growth Efficiencies and Self-Organization of TiO2 Nanotubes

被引:13
作者
Albu, Sergiu P. [1 ]
Taccardi, Nicola [2 ]
Paramasivam, Indhu [1 ]
Hebert, Kurt R. [3 ]
Schmuki, Patrik [1 ]
机构
[1] Univ Erlangen Nurnberg, Inst Surface Sci & Corros LKO, Dept Mat Sci, D-91058 Bavaria, Germany
[2] Univ Erlangen Nurnberg, Lehrstuhl Chem Reakt Tech CRT, D-91058 Bavaria, Germany
[3] Iowa State Univ, Dept Chem & Biol Engn, Ames, IA 50011 USA
关键词
RAPID ANODIC GROWTH; HIGH-ASPECT-RATIO; FORMATION DYNAMICS; POROUS OXIDE; FILMS; TITANIUM; ANODIZATION; MORPHOLOGY; ARRAYS; INITIATION;
D O I
10.1149/2.015208jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Self-organization of anodic oxide to TiO2 nanotubes has attracted in the past few years wide interest. Recent theoretical modeling predicted that self-organization occurs when the efficiency of oxide growth lies in the certain range specific to the anodized material. The present paper analyzes the experimental range of efficiencies during growth of self-organized TiO2 nanotubes and it compares the obtained results with the most advanced theoretical model on self-organization over a wide range of experimental conditions. The paper addresses in detail a number of critical experimental issues, which should be considered when oxide growth efficiencies of nanotubes are extracted. Finally we confront our data with theoretical predictions of stability regimes for the self-organization. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.015208jes] All rights reserved.
引用
收藏
页码:H697 / H703
页数:7
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