Highly Selective Hydroboration of Alkenes, Ketones and Aldehydes Catalyzed by a Well-Defined Manganese Complex

被引：163

作者：

Zhang, Guoqi ^{[1
,2
]}

Zeng, Haisu ^{[1
,2
,3
]}

Wu, Jing ^{[1
,2
,3
]}

Yin, Zhiwei ^{[1
,2
,3
]}

Zheng, Shengping ^{[3
]}

Fettinger, James C. ^{[4
]}

机构：

[1] CUNY, John Jay Coll, Dept Sci, New York, NY 10019 USA

[2] CUNY, PhD Chem Program, Grad Ctr, New York, NY 10019 USA

[3] CUNY, Hunter Coll, Dept Chem, New York, NY 10065 USA

[4] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 46期

基金：

美国国家科学基金会;

关键词：

alkenes; carbonyl compounds; hydroboration; manganese catalysis; Markovnikov selectivity; CROSS-COUPLING REACTIONS; ASYMMETRIC HYDROBORATION; ISOMERIZATION-HYDROBORATION; GRIGNARD-REAGENTS; COBALT CATALYSTS; HYDROSILYLATION; REDUCTION; LIGAND; REGIO; CHEMO;

D O I：

10.1002/anie.201607579

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Well-defined manganese complexes based on inexpensive, readily available ligands, 2,2': 6', 2 ''-terpyridine and its derivatives have been prepared and employed for the selective hydroboration of alkenes, ketones and aldehydes. Highly Markovnikov regioselective hydroboration of styrenes as well as excellent chemoselective hydroboration of ketones over alkenes were achieved, for the first time, by an earth-abundant manganese catalyst.

引用

页码：14367 / 14370

页数：4

共 74 条

[1]

[Anonymous], 2012, ANGEW CHEM

[2]

[Anonymous], 2001, ANGEW

[3]

[Anonymous], 2009, ANGEW CHEM

[4]

[Anonymous], 2015, ANGEW CHEM

[5]

[Anonymous], 1975, ORGANIC SYNTHESES VI

[6]

[Anonymous], 2016, Angew. Chem, DOI DOI 10.1002/ANGE.201605501

[7]

[Anonymous], 2014, Angew. Chem. Int. Ed

[8]

[Anonymous], ANGEW CHEM

[9]

[Anonymous], 2016, ANGEW CHE

[10] Manganese-Catalyzed Borylation of Unactivated Alkyl Chlorides [J].

Atack, Thomas C. ;

Cook, Silas P. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (19) :6139-6142

← 1 2 3 4 5 6 7 8 →