First structurally characterized triazinyl palladium complexes via oxidative addition of cyanuric chloride derivatives

被引：9

作者：

Braun, Markus ^{[1
]}

Frank, Walter ^{[1
]}

Ganter, Christian ^{[1
]}

机构：

[1] Univ Dusseldorf, Inst Anorgan Chem & Strukturchem, D-40225 Dusseldorf, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 22期

关键词：

Palladium; Cyanuric chloride; Triazine; Oxidative addition; CARBENE COMPLEXES; CRYSTAL-STRUCTURES; C-H; NITROGEN; LIGANDS; BOND; SUBSTITUTION; NICKEL(II); ACTIVATION; REACTIVITY;

D O I：

10.1016/j.jorganchem.2011.08.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of cyanuric chloride and two disubstituted derivatives with [Pd(PPh3)(4)] is described, leading to the trans-triazinyl complexes [(PPh3)(2)Pd(C3N3R2)Cl] 2a-c (R = Ph (a), t-Bu (b), Cl (c)) in good to excellent yield via oxidative addition. The complexes were fully characterized including X-ray structure determination. (C) 2011 Elsevier B. V. All rights reserved.

引用

页码：3580 / 3583

页数：4

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