Precise Micropatterning of a Porous Poly(ionic liquid) via Maskless Photolithography for High-Performance Nonenzymatic H2O2 Sensing

被引:32
作者
Yin, Ming-Jie [1 ]
Zhao, Qiang [2 ,3 ]
Wu, Jushuai [1 ]
Seefeldt, Karoline [3 ]
Yuan, Jiayin [3 ,4 ]
机构
[1] Hong Kong Polytech Univ, Photon Res Ctr, Dept Elect Engn, Hong Kong, Peoples R China
[2] Huazhong Univ Sci & Technol, Key Lab Mat Chem Energy Convers & Storage, Minist Educ, Sch Chem & Chem Engn, Wuhan 430074, Hubei, Peoples R China
[3] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14424 Potsdam, Germany
[4] Stockholm Univ, Dept Mat & Environm Chem MMK, Svante Arrhenius Vag 16 C, S-10691 Stockholm, Sweden
关键词
maskless photolithography; poly(ionic liquid); porous microstructures; nanoparticles; H2O2; sensors; HYDROGEN-PEROXIDE; ELECTROCHEMICAL DETECTION; AMPEROMETRIC BIOSENSOR; ION-GELS; SENSOR; NANOPARTICLES; GRAPHENE; MEMBRANES; CELLS; NANOTUBES;
D O I
10.1021/acsnano.8b07069
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Porous poly(ionic liquid)s (PILs) recently have been serving as a multifunctional, interdisciplinary materials platform in quite a few research areas, including separation, catalysis, actuator, sensor, and energy storage, just to name a few. In this context, the capability of photopatterning PIL microstructures in a porous state on a substrate is still missing but is a crucial step for their real industrial usage. Here, we developed a method for in situ rapid patterning of porous PIL microstructures via a maskless photolithography approach coupled with a simple electrostatic complexation treatment. This breakthrough enables design of miniaturized sensors. As exemplified in this work, upon loading Pt nanoparticles into porous PIL microstructures, the hybrid sensor showed outstanding performance, bearing both a high sensitivity and a wide detection range.
引用
收藏
页码:12551 / 12557
页数:7
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