Component recognition with three-dimensional fluorescence spectra based on non-negative matrix factorization

被引:8
作者
Yu, Shaohui [1 ,2 ]
Zhang, Yujun [1 ]
Liu, Wenqing [1 ]
Zhao, Nanjing [1 ]
Xiao, Xue [1 ]
Yin, Gaofang [1 ]
机构
[1] Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Key Lab Environm Opt & Technol, Hefei 230031, Peoples R China
[2] Hefei Normal Univ, Dept Math, Hefei 230061, Peoples R China
关键词
non-negative matrix factorization; three-dimensional fluorescence spectra; integrated similarity index; component recognition; TRILINEAR DECOMPOSITION ALGORITHM; IDENTIFICATION;
D O I
10.1002/cem.1404
中图分类号
TP [自动化技术、计算机技术];
学科分类号
0812 ;
摘要
Non-negative matrix factorization (NMF) is a widely used approach in signal processing. In this work, we apply it to the component recognition of mixtures with multicomponent three-dimensional fluorescence spectra. Compared with the popular PARAFAC for component recognition, NMF has the following advantages: on one hand, the decomposed spectra are three dimensional, and thus, more information can be obtained, which is beneficial for component recognition; on the other hand, the decomposed spectra are non-negative and thus have a certain physical significance. More importantly, we propose a type of integrated similarity indices for the three-dimensional fluorescence spectra, which, by construction, is good at component recognition from overlapping fluorescence spectra. Experiment results demonstrate that NMF combined with integrated similarity index provides an effective method for component recognition of multicomponent three-dimensional overlapping fluorescence spectra. Copyright (C) 2011 John Wiley & Sons, Ltd.
引用
收藏
页码:586 / 591
页数:6
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