Validation of bubble breakage, coalescence and mass transfer models for gas-liquid dispersion in agitated vessel

Bubble breakage and coalescence phenomena and multicomponent gas-liquid mass transfer were studied in a 194 dm(3) Rushton turbine agitated vessel. Local bubble size distributions (BSD) were measured from air-tap water system at several agitation conditions with capillary suction probe (CSP) technique. The CSP was compared to the digital imaging (131) and phase Doppler anemometry (PDA) techniques in a 14dm(3) stirred vessel. The volumetric BSDs between the CSP and DI were in agreement, but number BSDs showed notable deviation. The limitations of measurement techniques seem to be the main reason. A multiblock stirred tank model with discretized population balances for bubbles and two-film Maxwell-Stefan multicomponent mass transfer between gas and liquid was created for the 194dm(3) agitated vessel. The model considers local mass transfer conditions in the vessel and is simple enough for the mathematical optimization of unknown model parameters. Unknown parameters in the mechanistic bubble breakage and coalescence models were fitted against measured local BSDs. After this, a parameter in the liquid film mass transfer correlation was adjusted against absorption and desorption experiments of oxygen. Local gas-liquid mass transfer areas were calculated from the population balance model. The simulations with the validated models show good agreement against experiments. On the other hand, the fitted parameters deviate from the theoretical values, which emphasizes the need of model validation against accurate experiments. Due to their fundamental character and the validation process, the fitted models seem to be useful tools for the design and scale-up of agitated gas-liquid reactors. (c) 2005 Elsevier Ltd. All rights reserved.