Critics of non-isothermal kinetic methods to calculate the kinetic parameters

被引:0
作者
Popescu, C
Segal, E
Budrugeac, P
机构
[1] Rhein Westfal TH Aachen, DWI, D-5100 Aachen, Germany
[2] Univ Bucharest, Bucharest, Romania
[3] INCDIE, ICPE CA, Bucharest, Romania
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D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By surveying the most used methods for evaluating the kinetic parameters from non-isothermal measurements, we propose their classification scheme. As a result of the analysis we suggest a methodology to analyse the data from non-isothermal experiments and discuss several problems of non-isothermal kinetics, e.g., the validity of steady-state approximation under non-isothermal conditions and the problem of expressing the activation energy as a range of values.
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页码:511 / 518
页数:8
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