Two-Dimensional 3d-4f Networks Containing Planar Co4Ln2 Clusters with Single-Molecule-Magnet Behaviors

被引:105
作者
Liu, Yue [1 ,3 ]
Chen, Zhi [1 ,3 ]
Ren, Jia [1 ,3 ]
Zhao, Xiao-Qing [2 ]
Cheng, Peng [1 ,3 ]
Zhao, Bin [1 ,3 ]
机构
[1] Nankai Univ, MOE, Key Lab Adv Energy Mat Chem, Dept Chem, Tianjin 300071, Peoples R China
[2] Sichuan Agr Univ, Coll Life & Sci, Yaan 625014, Peoples R China
[3] Nankai Univ, Dept Chem, TKL Met & Mol Based Mat Chem, Tianjin 300071, Peoples R China
关键词
COMPLEXES; DY; PARAMETERS; MANGANESE;
D O I
10.1021/ic300372v
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two novel two-dimensional 3d-4f networks based on planar Co(4)Ln(2) clusters supported by rigid 4'-(4-carboxyphenyl)-2,2':6',2 ''-terpyridine afford the first examples of high-dimensional networks with 3d-4f clusters behaving as single-molecule magnets.
引用
收藏
页码:7433 / 7435
页数:3
相关论文
共 35 条
[1]   Series of Isostructural Planar Lanthanide Complexes [Ln4III(μ3-OH)2(mdeaH)2(piv)8] with Single Molecule Magnet Behavior for the Dy4 Analogue [J].
Abbas, Ghulam ;
Lan, Yanhua ;
Kostakis, George E. ;
Wernsdorfer, Wolfgang ;
Anson, Christopher E. ;
Powell, Annie K. .
INORGANIC CHEMISTRY, 2010, 49 (17) :8067-8072
[2]   Single Pyramid Magnets: Dy5 Pyramids with Slow Magnetic Relaxation to 40 K [J].
Blagg, Robin J. ;
Muryn, Christopher A. ;
McInnes, Eric J. L. ;
Tuna, Floriana ;
Winpenny, Richard E. P. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (29) :6530-6533
[3]   Molecular spintronics using single-molecule magnets [J].
Bogani, Lapo ;
Wernsdorfer, Wolfgang .
NATURE MATERIALS, 2008, 7 (03) :179-186
[4]   CoII chemistry of 2,6-bis(2-pyridylcarbonyl)pyridine:: An icosanuclear Co cluster exhibiting superparamagnetic relaxation [J].
Boudalis, AK ;
Raptopoulou, CP ;
Abarca, B ;
Ballesteros, R ;
Chadlaoui, M ;
Tachagues, JP ;
Terzis, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (03) :432-435
[5]   BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].
BROWN, ID ;
ALTERMATT, D .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247
[6]   A Tetragonal 2D Array of Single-Molecule Magnets with Modulated Collective Behavior [J].
Burzuri, Enrique ;
Campo, Javier ;
Falvello, Larry R. ;
Forcen-Vazquez, Elena ;
Luis, Fernando ;
Mayoral, Isabel ;
Palacio, Fernando ;
Saenz de Pipaon, Cristina ;
Tomas, Milagros .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (10) :2818-2822
[7]   Synthesis, Structure, and Magnetism of Heterobimetallic Trinuclear Complexes {[L2Co2Ln][X]} [Ln = Eu, X = Cl; Ln = Tb Dy, Ho, X = NO3; LH3 = (S)P[N(Me)N=CH-C6H3-2-OH-3-OMe]3]: A 3d-4f Family of Single-Molecule Magnets [J].
Chandrasekhar, Vadapalli ;
Pandian, Balasubramanian Murugesa ;
Vittal, Jagadese J. ;
Clerac, Rodolphe .
INORGANIC CHEMISTRY, 2009, 48 (03) :1148-1157
[8]  
Gatteschi D, 2006, MESOSCOPIC PHYS NANO, P1
[9]   Manifestation of Spin Selection Rules on the Quantum Tunneling of Magnetization in a Single-Molecule Magnet [J].
Henderson, J. J. ;
Koo, C. ;
Feng, P. L. ;
del Barco, E. ;
Hill, S. ;
Tupitsyn, I. S. ;
Stamp, P. C. E. ;
Hendrickson, D. N. .
PHYSICAL REVIEW LETTERS, 2009, 103 (01)
[10]   Quantum coherence in an exchange-coupled dimer of single-molecule magnets [J].
Hill, S ;
Edwards, RS ;
Aliaga-Alcalde, N ;
Christou, G .
SCIENCE, 2003, 302 (5647) :1015-1018