Photocatalytic aerobic cross-coupling reaction of N-substituted anilines with N-aryl glycine esters: Synthesis of α-aryl α-amino esters

被引：22

作者：

Sun, Bin ^{[1
]}

Deng, Jiacheng ^{[2
]}

Li, Deyu ^{[2
]}

Jin, Can ^{[2
]}

Su, Weike ^{[1
,2
]}

机构：

[1] Zhejiang Univ Technol, Collaborat Innovat Ctr Yangtze River Delta Reg Gr, Hangzhou 310014, Zhejiang, Peoples R China

[2] Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou 310014, Zhejiang, Peoples R China

来源：

TETRAHEDRON LETTERS | 2018年 / 59卷 / 49期

基金：

中国国家自然科学基金;

关键词：

Cross dehydrogenative coupling; Photocatalysis; C-C bond formation; alpha-Aryla alpha-amino esters; Metal-free; VISIBLE-LIGHT PHOTOREDOX; CATALYZED OXIDATIVE CYANATION; TRANSITION-METAL; CARBONYL-COMPOUNDS; HYDROGEN-PEROXIDE; TERTIARY-AMINES; ACID CATALYSIS; ARYLATION; FUNCTIONALIZATION; DERIVATIVES;

D O I：

10.1016/j.tetlet.2018.10.067

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel photocatalytic cross dehydrogenative coupling reaction of N-aryl glycine esters with N-substituted anilines has been developed. The reaction proceeds effectively using methylene blue as a photocatalyst under visible light irradiation without any metal, chemical oxidant or additive. A variety of alpha-aryl alpha-amino derivatives were prepared in moderate to excellent yields with a high para-regioselectivity. (C) 2018 Elsevier Ltd. All rights reserved.

引用

页码：4364 / 4369

页数：6

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