Poly(vinylidene fluoride)-based macroporous separators for supercapacitors

被引：55
|
作者：
Karabelli, D. [1 ]
Lepretre, J-C [1 ]
Alloin, F. [1 ]
Sanchez, J-Y [1 ]
机构：
[1] Univ Grenoble 1, Grenoble INP, Univ Savoie, LEPMI,CNRS,UMR 5279, F-38402 St Martin Dheres, France
来源：
ELECTROCHIMICA ACTA | 2011年 / 57卷
关键词：
PVdF; PVdF-HFP; Macroporous separator; Phase inversion; Supercapacitor; LITHIUM-ION BATTERIES; POLYMER ELECTROLYTES; PHASE-SEPARATION; MEMBRANES; GEL; CONDUCTIVITY; POLYANILINE; SOLVENT;
D O I：
10.1016/j.electacta.2011.03.033
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Macroporous polymer separators based on poly(vinylidene fluoride) (PVdF) and several VdF copolymers were prepared by a phase inversion process using acetone as a solvent. The resulting macroporous separators were characterized in terms of morphology, swelling behaviour, thermal and mechanical properties and ionic conductivity. The PVdF separator had a highly porous structure (80%) and exhibited good mechanical properties. Once filled by a molar solution of tetraethylammonium tetrafluoroborate (TEABF(4)) in acetonitrile (AN) it provided enhanced conductivity (18 mS cm(-1) at 25 degrees C) compared with commercial cellulose and Celgard (TM) separators. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：98 / 103
页数：6
相关论文
共 50 条
  • [41] Silica fillers for enhancement of dielectric properties of poly(vinylidene fluoride) and its copolymer
    Khair, Mehreen
    Rashid, Rubaya
    Ahmed, Saika
    Susan, Md Abu Bin Hasan
    MATERIALS TODAY-PROCEEDINGS, 2020, 29 : 1239 - 1245
  • [42] Viscoelastic and pressure-volume-temperature properties of poly(vinylidene fluoride) and poly(vinylidene fluoride)-hexafluoropropylene copolymers
    Mekhilef, N
    JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 80 (02) : 230 - 241
  • [43] Carbon nanotubes induced poly(vinylidene fluoride) crystallization from a miscible poly(vinylidene fluoride)/poly(methyl methacrylate) blend
    Feng, Chen-xia
    Huang, Ting
    Chen, Hai-ming
    Yang, Jing-hui
    Zhang, Nan
    Wang, Yong
    Zhang, Chao-liang
    Zhou, Zuo-wan
    COLLOID AND POLYMER SCIENCE, 2014, 292 (12) : 3279 - 3290
  • [44] Development of all-solid-state mediator-enhanced supercapacitors with polyvinylidene fluoride/lithium trifluoromethanesulfonate separators
    Zhou, Juanjuan
    Cai, Jinshu
    Cai, Sirui
    Zhou, Xiangyang
    Mansour, Azzam N.
    JOURNAL OF POWER SOURCES, 2011, 196 (23) : 10479 - 10483
  • [45] Preparation of Poly(vinylidene fluoride)/Poly(methyl methacrylate) Membranes by Novel Electrospinning System for Lithium Ion Batteries
    Li, Xiaoyun
    Cao, Qi
    Wang, Xianyou
    Jiang, Shenghui
    Deng, Huayang
    Wu, Na
    JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 122 (04) : 2616 - 2620
  • [46] Porous poly(vinylidene fluoride) membrane with highly hydrophobic surface
    Peng, M
    Li, HB
    Wu, LJ
    Zheng, Q
    Chen, Y
    Gu, WF
    JOURNAL OF APPLIED POLYMER SCIENCE, 2005, 98 (03) : 1358 - 1363
  • [47] Free-standing intrinsically conducting polymer membranes based on cellulose and poly(vinylidene fluoride) for energy storage applications
    Salado, Manuel
    Lanceros-Mendez, Senentxu
    Lizundia, Erlantz
    EUROPEAN POLYMER JOURNAL, 2021, 144
  • [48] Evaluation of the main processing parameters influencing the performance of poly(vinylidene fluoride–trifluoroethylene) lithium-ion battery separators
    C. M. Costa
    V. Sencadas
    J. G. Rocha
    M. M. Silva
    S. Lanceros-Méndez
    Journal of Solid State Electrochemistry, 2013, 17 : 861 - 870
  • [49] Gelation Behavior of Poly(Vinylidene Fluoride)-based Gel Polymer Electrolyte
    王标兵
    顾利霞
    Journal of Donghua University(English Edition), 2006, (03) : 74 - 78
  • [50] Ternary Diagrams of Poly(vinylidene fluoride) and Poly[(vinylidene fluoride)-co-hexafluoropropene] in Propylene Carbonate and Dimethyl Sulfoxide
    Akkoyun, Meral
    Carrot, Christian
    Blottiere, Benoit
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2012, 213 (05) : 587 - 593
12345