Catalytic Reduction of Dinitrogen to Ammonia by Use of Molybdenum-Nitride Complexes Bearing a Tridentate Triphosphine as Catalysts

被引：203

作者：

Arashiba, Kazuya ^{[1
]}

Kinoshita, Eriko ^{[1
]}

Kuriyama, Shogo ^{[1
]}

Eizawa, Aya ^{[1
]}

Nakajima, Kazunari ^{[1
]}

Tanaka, Hiromasa ^{[2
]}

Yoshizawa, Kazunari ^{[2
,3
,4
]}

Nishibayashi, Yoshiaki ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Inst Engn Innovat, Bunkyo Ku, Tokyo 1138656, Japan

[2] Kyoto Univ, ESICB, Nishikyo Ku, Kyoto 6158520, Japan

[3] Kyushu Univ, Inst Mat Chem & Engn, Nishi Ku, Fukuoka 8190395, Japan

[4] Kyushu Univ, Int Res Ctr Mol Syst, Nishi Ku, Fukuoka 8190395, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 17期

关键词：

MOLECULAR NITROGEN; COORDINATED DINITROGEN; MONO(DINITROGEN) COMPLEXES; PRODUCE AMMONIA; TRIPOD LIGAND; C-ATOM; N-2; ACTIVATION; CLEAVAGE; CONVERSION;

D O I：

10.1021/jacs.5b02579

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Newly designed and prepared molybdenum-nitride complexes bearing a mer-tridentate triphosphine as a ligand have been found to work as the most effective catalysts toward the catalytic reduction of dinitrogen to ammonia under ambient conditions, where up to 63 equiv of ammonia based on the Mo atom of the catalyst were produced.

引用

页码：5666 / 5669

页数：4

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