Efficient stereospecific syntheses of chiral ruthenium dimers

被引：73

作者：

MacDonnell, FM

Bodige, S

机构：

[1] Department of Chemistry, University of Texas at Arlington, Arlington

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 20期

关键词：

D O I：

10.1021/ic9605682

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The stereospecific synthesis of three isomeric Ru dimers, Delta,Delta-[(phen)(2)Ru(tpphz)Ru(phen)(2)](4+) (Delta,Delta-4) (where tpphz = tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2'',3''-j]-phenazine), Lambda,Lambda-4, and Lambda,Delta-4, can be accomplished in high yield with retention of optical activity by the formation of a phenazine ring between appropriately functionalized chiral precursors.

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页码：5758 / &

页数：3

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