Eu-doped Ca2SiO4 as a New Radio-photoluminescence Phosphor

被引:31
作者
Asada, Shota [1 ]
Okada, Go [1 ]
Kato, Takumi [1 ]
Nakamura, Fumiya [1 ]
Kawano, Naoki [1 ]
Kawaguchi, Noriaki [1 ]
Yanagida, Takayuki [1 ]
机构
[1] Nara Inst Sci & Technol NAIST, 8916-5 Takayama Cho, Nara 6300192, Japan
基金
日本科学技术振兴机构;
关键词
Radio-photoluminescence phosphor; Ca2SiO4; ceramics; Eu-doped; RPL MATERIAL; DOSIMETRY; CRYSTAL; GLASSES;
D O I
10.1246/cl.170940
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Eu-doped Ca2SiO4 ceramics have been newly found to show radio-photoluminescence (RPL). An as-prepared material shows photoluminescence (PL) only due to Eu3+ whereas an additional broad emission due to Eu2+ appears in the red region as a result of RPL after X-ray irradiation. The RPL is attributed to the intravalence conversion of the Eu ion (Eu3+ -> Eu2+), and this response can be detected as low as 10 mGy of X-ray dose.
引用
收藏
页码:59 / 61
页数:3
相关论文
共 22 条
[1]  
Akselrod M. S., OPTICAL DATA STORAGE, P244
[2]   Binding energies of Eu2+ and Eu3+ ions in β-Ca2SiO4 doped with europium [J].
Baran, Anna ;
Barzowska, Justyna ;
Grinberg, Marek ;
Mahlik, Sebastian ;
Szczodrowski, Karol ;
Zorenko, Yuriy .
OPTICAL MATERIALS, 2013, 35 (12) :2107-2114
[3]   Valency conversion of samarium ions under high dose synchrotron generated X-ray radiation [J].
Belev, George ;
Okada, Go ;
Tonchev, Dancho ;
Koughia, Cyril ;
Varoy, Chris ;
Edgar, Andy ;
Wysokinski, Tomasz ;
Chapman, Dean ;
Kasap, Safa .
PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 8, NO 9, 2011, 8 (09) :2822-2825
[4]   High-resolution X-ray imaging with samarium-doped fluoroaluminate and fluorophosphate glass [J].
Edgar, A. ;
Varoy, C. R. ;
Koughia, C. ;
Okada, G. ;
Belev, G. ;
Kasap, S. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2013, 377 :124-128
[5]   ROOM-TEMPERATURE PERSISTENT HOLE-BURNING OF SM2+ IN OXIDE GLASSES [J].
HIRAO, K ;
TODOROKI, S ;
CHO, DH ;
SOGA, N .
OPTICS LETTERS, 1993, 18 (19) :1586-1587
[6]   The role of silver in the radiophotoluminescent properties in silver-activated phosphate glass and sodium chloride crystal [J].
Kurobori, Toshio ;
Zheng, Wang ;
Miyamoto, Yuka ;
Nanto, Hidehito ;
Yamamoto, Takayoshi .
OPTICAL MATERIALS, 2010, 32 (09) :1231-1236
[7]   LIF DOSIMETRY BASED ON RADIOPHOTOLUMINESCENCE (RFL) [J].
LEVITA, M ;
SCHLESINGER, T ;
FRIEDLAND, SS .
IEEE TRANSACTIONS ON NUCLEAR SCIENCE, 1976, 23 (01) :667-674
[8]   Optically stimulated luminescence dosimetry [J].
McKeever, SWS .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2001, 184 (1-2) :29-54
[9]   Three-dimensional optical memory with rewriteable and ultrahigh density using the valence-state change of samarium ions [J].
Miura, K ;
Qiu, JR ;
Fujiwara, S ;
Sakaguchi, S ;
Hirao, K .
APPLIED PHYSICS LETTERS, 2002, 80 (13) :2263-2265
[10]   Emission mechanism of radiophotoluminescence in Ag-doped phosphate glass [J].
Miyamoto, Y. ;
Yamamoto, T. ;
Kinoshita, K. ;
Koyama, S. ;
Takei, Y. ;
Nanto, H. ;
Shimotsuma, Y. ;
Sakakura, M. ;
Miura, K. ;
Hirao, K. .
RADIATION MEASUREMENTS, 2010, 45 (3-6) :546-549