(SP-4-2)-Chlorido{N-[2-(diphenylphosphanyl)benzylidene]benzylamine-κ2P,N}(methyl)palladium(II)

被引：4

作者：

Chiririwa, Haleden ^{[1
]}

Meijboom, Reinout ^{[1
]}

机构：

[1] Univ Johannesburg, Res Ctr Synth & Catalysis, Dept Chem, ZA-2006 Johannesburg, South Africa

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

基金：

新加坡国家研究基金会;

关键词：

IMINOPHOSPHINE COMPLEXES; PALLADIUM(II) COMPLEXES;

D O I：

10.1107/S1600536811040074

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title Pd-II complex, [Pd(CH3)Cl(C26H22NP)], the Pd-II atom is coordinated in a slightly distorted square-planar geometry by the imino N and phosphane P atoms of the ligand, by one chloride ion and by a methyl ligand. The methyl group is trans to the N atom of the ligand.

引用

页码：M1498 / +

页数：10

共 10 条

[1]

Barbour L.J., 2001, J SUPRAMOL CHEM, V1, P189, DOI [DOI 10.1016/S1472-7862(02)00030-8, 10.1016/S1472-7862(02)00030-8]

[2]

Bruker, 2007, APEX2 SAINT PLUS XPR

[3] Dichlorido{N-[2-(diphenylphosphanyl)benzylidene]isopropylamine-κ2N,P}palladium(II) dimethyl sulfoxide monosolvate [J].

Chiririwa, Haleden ;

Meijboom, Reinout ;

Omondi, Bernard .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 :M608-U964

[4] Palladium(II) complexes with the bidentate iminophosphine ligand [Ph2PCH2C(Ph)=N(2,6-Me2C6H3)] [J].

Coleman, KS ;

Green, MLH ;

Pascu, SI ;

Rees, NH ;

Cowley, AR ;

Rees, LH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (22) :3384-3395

[5] RHODIUM IMINOPHOSPHINE COMPLEXES AS EFFICACIOUS OXYGEN CARRIERS - CRYSTAL-STRUCTURE OF A REPRESENTATIVE DIOXYGEN ADDUCT [J].

GHILARDI, CA ;

MIDOLLINI, S ;

MONETI, S ;

ORLANDINI, A ;

SCAPACCI, G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (23) :3371-3376

[6] Bis(pentafluorophenyl)nickel(II) complexes with α-diimines and iminophosphines [J].

Sanchez, G ;

Serrano, JL ;

Ruiz, F ;

Lopez, G .

JOURNAL OF FLUORINE CHEMISTRY, 1998, 91 (02) :165-169

[7] Palladium(II) iminophosphine complexes [J].

Sánchez, G ;

Momblona, F ;

Pérez, J ;

López, G ;

Serrano, JL ;

Liu, M ;

Sanz, F .

TRANSITION METAL CHEMISTRY, 2001, 26 (1-2) :100-104

[8] New cyclometalated palladium(II) complexes with iminophosphines crystal structures of [Pd(CXN)(o-Ph2PC6H4-CH=NR)][PF6] (CXN=azobenzene, R=Et; CXN=2-phenylpyridine, R=Me) [J].

Sánchez, G ;

Serrano, JL ;

Moral, MA ;

Pérez, J ;

Molins, E ;

López, G .

POLYHEDRON, 1999, 18 (23) :3057-3064

[9]

Sheldrick G.M., 1997, SADABS

[10] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

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