The synthesis of deuteriated tri-tert-butyl phosphine

被引：1

作者：

Brown, Lucy C. ^{[1
]}

McGrogan, Anne ^{[1
]}

Delavoux, Yoan ^{[1
]}

Hogg, James M. ^{[1
,2
]}

Holbrey, John D. ^{[1
]}

Gunaratne, H. Q. Nimal ^{[1
]}

Swadzba-Kwasny, Malgorzata ^{[1
]}

Tellam, James P. ^{[3
]}

Youngs, Sarah E. ^{[3
]}

机构：

[1] Queens Univ Belfast, Sch Chem & Chem Engn, QUILL Res Ctr, Belfast BT9 5AG, Antrim, North Ireland

[2] Univ Bath, Dept Chem Engn, Bath, Avon, England

[3] Rutherford Appleton Lab, ISIS Neutron & Muon Source, Harwell Campus, Didcot OX11 0QX, Oxon, England

来源：

JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS | 2022年 / 65卷 / 13期

关键词：

Grignard; perdeuteriated; perdeuteriated ligands; phosphine; phosphine frustrated Lewis pairs; PtBu3; transition metal catalysis; tri-tert-butyl phosphine;

D O I：

10.1002/jlcr.4001

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The synthesis of deuteriated tri-tert-butyl phosphine is reported. This synthesis is an adaptation of the known procedure for tri-tert-butyl phosphine via a Grignard intermediate.

引用

页码：338 / 342

页数：5

共 18 条

[1]

Baudler M., 1989, INORG SYN, P1

[2] Frustrated Lewis pairs in ionic liquids and molecular solvents - a neutron scattering and NMR study of encounter complexes [J].