Photocatalytic decomposition of organic contaminants by Bi2WO6 under visible light irradiation

被引:519
作者
Tang, JW
Zou, ZG
Ye, JH
机构
[1] NIMS, Ecomat Ctr, Tsukuba, Ibaraki 3050047, Japan
[2] Nanjing Univ, EEMC, Nanjing 210093, Peoples R China
[3] Natl Inst Adv Ind Sci & Technol, PCRC, Tsukuba, Ibaraki 3058565, Japan
关键词
Bi2WO6; photocatalyst; organic contaminants; visible light irradiation;
D O I
10.1023/B:CATL.0000011086.20412.aa
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An oxide photocatalyst Bi2WO6 with corner-shared WO6 octahedral layered structure was synthesized. Its band gap was determined to be 2.69 eV from UV - vis diffuse reflectance spectra. The photocatalyst showed not only the activity for photocatalytic O-2 evolution with the initial evolution rate of 2.0 mumol/h but also the activity of mineralizing both CHCl3 and CH3CHO contaminants under visible light irradiation. Meanwhile, wavelength dependence of CH3CHO decomposition was observed, which indicated that the photocatalytic activity of the photocatalyst was in good agreement with its light-absorption ability.
引用
收藏
页码:53 / 56
页数:4
相关论文
共 14 条
  • [1] Visible-light photocatalysis in nitrogen-doped titanium oxides
    Asahi, R
    Morikawa, T
    Ohwaki, T
    Aoki, K
    Taga, Y
    [J]. SCIENCE, 2001, 293 (5528) : 269 - 271
  • [2] Photocatalytic transformations of chlorinated methanes in the presence of electron and hole scavengers
    Calza, P
    Minero, C
    Pelizzetti, E
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1997, 93 (21): : 3765 - 3771
  • [3] ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS
    HOFFMANN, MR
    MARTIN, ST
    CHOI, WY
    BAHNEMANN, DW
    [J]. CHEMICAL REVIEWS, 1995, 95 (01) : 69 - 96
  • [4] Efficient photochemical water splitting by a chemically modified n-TiO2 2
    Khan, SUM
    Al-Shahry, M
    Ingler, WB
    [J]. SCIENCE, 2002, 297 (5590) : 2243 - 2245
  • [6] Photocatalytic degradation of 4-n-nonylphenol under irradiation from solar simulator:: Comparison between BiVO4 and TiO2 photocatalysts
    Kohtani, S
    Makino, S
    Kudo, A
    Tokumura, K
    Ishigaki, Y
    Matsunaga, T
    Nikaido, O
    Hayakawa, K
    Nakagaki, R
    [J]. CHEMISTRY LETTERS, 2002, (07) : 660 - 661
  • [7] AgInZn7S9 solid solution photocatalyst for H2 evolution from aqueous solutions under visible light irradiation
    Kudo, A
    Tsuji, I
    Kato, H
    [J]. CHEMICAL COMMUNICATIONS, 2002, (17) : 1958 - 1959
  • [8] H2 or O2 evolution from aqueous solutions on layered oxide photocatalysts consisting of Bi3+ with 6s2 configuration and d0 transition metal ions
    Kudo, A
    Hijii, S
    [J]. CHEMISTRY LETTERS, 1999, (10) : 1103 - 1104
  • [9] A novel aqueous process for preparation of crystal form-controlled and highly crystalline BiVO4 powder from layered vanadates at room temperature and its photocatalytic and photophysical properties
    Kudo, A
    Omori, K
    Kato, H
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (49) : 11459 - 11467
  • [10] Synthesis of nitrogen-containing ZnO powders by spray pyrolysis and their visible-light photocatalysis in gas-phase acetaldehyde decomposition
    Li, D
    Haneda, H
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2003, 155 (1-3) : 171 - 178