One-pot synthesis of α-amino phosphonates using samarium diiodide as a catalyst precursor

被引：106

作者：

Xu, F ^{[1
]}

Luo, YQ ^{[1
]}

Deng, MY ^{[1
]}

Shen, Q ^{[1
]}

机构：

[1] Suzhou Univ, Dept Chem, Suzhou 215006, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 2003卷 / 24期

关键词：

samarium; iodine; synthetic methods; lanthanides;

D O I：

10.1002/ejoc.200300545

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and efficient preparation of alpha-amino phosphonates under relatively mild conditions by the one-pot reaction of aldehydes with amines and dialkyl phosphites using catalytic amounts of SmI2 is described. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

引用

收藏

页码：4728 / 4730

页数：3

相关论文

共 12 条

[1] Lanthanide iodides, a new family of efficient Lewis acid catalysts [J].

Collin, J ;

Giuseppone, N ;

Van de Weghe, P .

COORDINATION CHEMISTRY REVIEWS, 1998, 178 :117-144

[2] THE ORGANOMETALLIC CHEMISTRY OF THE LANTHANIDE ELEMENTS IN LOW OXIDATION-STATES [J].

EVANS, WJ .

POLYHEDRON, 1987, 6 (05) :803-835

[3] THE REACTION OF SAMARIUM(III) IODIDE WITH SAMARIUM METAL IN TETRAHYDROFURAN - A NEW METHOD FOR THE PREPARATION OF SAMARIUM(II) IODIDE [J].

IMAMOTO, T ;

ONO, M .

CHEMISTRY LETTERS, 1987, (03) :501-502

[4] Lanthanide triflate-catalyzed three component synthesis of α-amino phosphonates in ionic liquids.: A catalyst reactivity and reusability study [J].

Lee, SG ;

Park, JH ;

Kang, J ;

Lee, JK .

CHEMICAL COMMUNICATIONS, 2001, (17) :1698-1699

[5] Facile synthesis of α-amino phosphonates in water using a Lewis acid-surfactant-combined catalyst [J].

Manabe, K ;

Kobayashi, S .

CHEMICAL COMMUNICATIONS, 2000, (08) :669-670

[6] ESTERS CONTAINING PHOSPHORUS .1. [J].

MCCOMBIE, H ;

SAUNDERS, BC ;

STACEY, GJ .

JOURNAL OF THE CHEMICAL SOCIETY, 1945, (MAY) :380-382

[7] EFFICIENT FORMATION OF PINACOLS FROM ALDEHYDES OR KETONES MEDIATED BY SAMARIUM DIIODIDE [J].

NAMY, JL ;

SOUPPE, J ;

KAGAN, HB .

TETRAHEDRON LETTERS, 1983, 24 (08) :765-766

[8] One-pot synthesis of α-amino phosphonates from aldehydes using lanthanide triflate as a catalyst [J].

Qian, CT ;

Huang, TS .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (12) :4125-4128

[9] General procedure for the synthesis of α-amino phosphonates from aldehydes and ketones using indium(III) chloride as a catalyst [J].

Ranu, BC ;

Hajra, A ;

Jana, U .

ORGANIC LETTERS, 1999, 1 (08) :1141-1143

[10] SOME ORGANIC-REACTIONS PROMOTED BY SAMARIUM DIIODIDE [J].

SOUPPE, J ;

DANON, L ;

NAMY, JL ;

KAGAN, HB .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 250 (01) :227-236