The fixation and reduction of dinitrogen using lanthanides: praseodymium and neodymium meso-octaethylporphyrinogen-dinitrogen complexes

被引：88

作者：

Campazzi, E ^{[1
]}

Solari, E ^{[1
]}

Floriani, C ^{[1
]}

Scopelliti, R ^{[1
]}

机构：

[1] Univ Lausanne, BCH, Inst Chim Minerale & Analyt, CH-1015 Lausanne, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 23期

关键词：

D O I：

10.1039/a807405d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The meso-octaethylporphyrinogen-sodium-lanthanide complexes, [{(eta(5) : eta(1) : eta(5) : eta(1)-Et8N4)M}Na(thf)(2)], in the presence of Na metal and under a nitrogen atmosphere, fix and reduce dinitrogen to the [N-2](2-) anion, as shown by the isolation of the dinuclear complexes containing the [M(mu-eta(2) : eta(2)-N-2)M] moiety [M = Pr, Nd].

引用

页码：2603 / 2604

页数：2

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