The solid-state synthesis of metal nanoparticles from organometallic precursors

被引：25
作者：
Wostek-Wojciechowska, D
Jeszka, JK
Amiens, C
Chaudret, B
Lecante, P
机构：
[1] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90364 Lodz, Poland
[2] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France
[3] CNRS, Ctr Elaborat Mat Etudes Struct, F-31055 Toulouse, France
来源：
JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2005年 / 287卷 / 01期
关键词：
metal nanoparticles; polymer; organometallic precursor; dihydrogen; TEM; WAXS;
D O I：
10.1016/j.jcis.2005.01.109
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Nanoparticles (NPs), average size of 2-5 nm, of ruthenium, cobalt, and rhodium have been prepared by an original method, namely the solid-state decomposition under dihydrogen of an organometallic precursor either dispersed in polymer films or directly as nanocrystals. The NPs dispersion, size, and morphology are investigated by transmission electron microscopy, and their structure by wide angle X-ray scattering. Infrared spectroscopy, after adsorption of carbon monoxide on the metal NPs Surfaces, evidences a nonoxidized surface of high reactivity. (c) 2005 Elsevier Inc. All rights reserved.
引用
收藏
页码：107 / 113
页数：7
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