Crystalline structure of mixed metal oxide catalysts for propane selective oxidation to acrylic acid

被引：4

作者：

Yu Zhen-xing ^{[1
]}

Zheng Wei ^{[1
]}

Xu Wen-long ^{[1
]}

Zhang Ping ^{[1
]}

Fu Hong-ying ^{[1
]}

Zhang Yu-hang ^{[1
]}

机构：

[1] Daqing Nanyuan Grp Co Ltd, Ctr Res & Dev, Daqing 163517, Peoples R China

来源：

TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA | 2011年 / 21卷

关键词：

crystalline structure; propane oxidation; selective oxidation; acrylic acid; XRD; MO-V-TE; M1 ACTIVE PHASE;

D O I：

10.1016/S1003-6326(11)61615-4

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

The effects of the preparation procedure on the formation of crystal phases and catalytic performance of the MoVTeNbO mixed metal oxide catalysts in selective oxidation of propane to acrylic acid were investigated. The results show that the preferred drying method is the rotavapor method, which favors the formation of an effective crystal phase and suppresses the formation of impurity phases. The preferred calcination atmosphere is an Ar atmosphere. The MoVTeNb mixed metal oxide catalysts can be obtained by solution method after heat-treatment at 600 degrees C in an Ar atmosphere, via a rotavapor with a warm water bath at 60 degrees C, and a pH value of 4.0. The catalyst with a MoVTeNb molar ratio of 1.0:0.3:0.23:0.12 is the most effective and extremely active.

引用

页码：S405 / S411

页数：7

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