Copper(I) Complexes with Anionic Acylthio- or Acylselenourea Ligands and N-Heterocyclic Carbenes or Phosphanes

被引：10

作者：

Kuchar, Julia ^{[1
]}

Rust, Joerg ^{[2
]}

Lehmann, Christian W. ^{[2
]}

Mohr, Fabian ^{[1
]}

机构：

[1] Berg Univ Wuppertal, Fak Math & Nat Wissensch, Anorgan Chem, Gaussstr 20, D-42119 Wuppertal, Germany

[2] Max Planck Inst Kohlenforsch, Chem Kristallog & Elekt Mikroskopie, Kaiser Wilhelm Pl 1, D-45470 Mulheim, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2018年 / 48期

关键词：

Copper; Selenium; N-Heterocyclic Carbenes; X-ray crystallography; CATALYTIC-OXIDATION PROPERTY; TRANSITION-METAL-COMPLEXES; CRYSTAL-STRUCTURES; EPR-INVESTIGATIONS; MOLECULAR-STRUCTURE; SINGLE-CRYSTAL; CU-II; CU(I); DEPOSITION; COORDINATION;

D O I：

10.1002/ejic.201801007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Copper(I) complexes containing acylthio- and selenoureato ligands can be accessed either by transmetallation from the corresponding silver compounds or by direct reaction of the acylthio/selenourea with a copper(I) precursor in the presence of base. Several examples of tricoordinate organocopper(I) complexes containing N-heterocyclic carbenes as well as tetrahedral bis(phosphane) copper(I) compounds are reported with their spectroscopic and structural characterization.

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收藏

页码：5215 / 5222

页数：8

相关论文

共 54 条

[1] Phase-Controlled Deposition of Copper Sulfide Thin Films by Using Single-Molecular Precursors [J].

Ashraf, Saba ;

Saeed, Aamer ;

Malik, Mohammad Azad ;

Floerke, Ulrich ;

Bolte, Michael ;

Haider, Naghmah ;

Akhtar, Javeed .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 2014 (03) :533-538

[2] SYNTHESIS AND CHARACTERIZATION OF NEW TRANSITION-METAL CHELATES OF 1,1-DIALKYL-3-BENZOYL-THIOUREAS [J].

BEYER, L ;

HOYER, E ;

HENNIG, H ;

KIRMSE, R ;

HARTMANN, H ;

LIEBSCHER, J .

JOURNAL FUR PRAKTISCHE CHEMIE, 1975, 317 (05) :829-839

[3]

Beyer L., 1983, REV COLOMB QUIM, V12, P69

[4] Simultaneous formation of both novel bis(μ-sulfur)- and bis(μ-oxo)bridged copper(II) dimers by reaction of N-benzoyl-N′,N′-dimethylthiourea (HL) with CuCl2.: Syntheses, crystal structures and magnetic properties of [{CuL(HL)Cl}2] and [{CuL2}2] [J].

Che, DJ ;

Li, G ;

Yao, XL ;

Zhou, YZ ;

Zhou, DP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (16) :2683-2687

[5]

COTTON FA, 1960, J CHEM SOC, P5267

[6] Addition of s-h bonds across electron-deficient olefins catalyzed by well-defined copper(I) thiolate complexes [J].

Delp, Samuel A. ;

Munro-Leighton, Colleen ;

Goj, Laurel A. ;

Ramirez, Magaly A. ;

Gunnoe, T. Brent ;

Petersen, Jeffrey L. ;

Boyle, Paul D. .

INORGANIC CHEMISTRY, 2007, 46 (07) :2365-2367

[7] Acylchalcogenourea Complexes of Silver(I) [J].

Doerner, Maik ;

Rautiainen, J. Mikko ;

Rust, Joerg ;

Lehmann, Christian W. ;

Mohr, Fabian .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (04) :789-797

[8] OLEX2: a complete structure solution, refinement and analysis program [J].

Dolomanov, Oleg V. ;

Bourhis, Luc J. ;

Gildea, Richard J. ;

Howard, Judith A. K. ;

Puschmann, Horst .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 :339-341

[9] Acylselenoureas [J].

Douglass, IB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1937, 59 :740-742

[10] Some derivatives of benzoyl and furoyl isothiocyanates and their use in synthesizing heterocyclic compounds [J].

Douglass, IB ;

Dains, FB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1934, 56 :719-721

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