Reverse micelle facilitated synthesis of nanostructured polyaniline as the counter electrode materials in dye-sensitized solar cells

被引：13

作者：

Utami, Annisa Nurul ^{[1
]}

Reza, Muhammad ^{[1
]}

Benu, Didi Prasetyo ^{[1
,2
]}

Fatya, Alvian Ikhsanul ^{[1
]}

Yulianto, Brian ^{[3
,4
]}

Suendo, Veinardi ^{[1
,4
]}

机构：

[1] Inst Teknol Bandung, Fac Math & Nat Sci, Div Inorgan & Phys Chem, Bandung, Indonesia

[2] Univ Timor, Dept Chem, Kefamenanu, Indonesia

[3] Inst Teknol Bandung, Dept Engn Phys, Bandung, Indonesia

[4] Inst Teknol Bandung, Res Ctr Nanosci & Nanotechnol, Bandung, Indonesia

来源：

POLYMER-PLASTICS TECHNOLOGY AND MATERIALS | 2020年 / 59卷 / 12期

关键词：

Counter-electrode materials; dye-sensitized solar cell; emulsion polymerization; nanostructured polyaniline; polyglyceryl-2-dipolyhydroxystearate; reverse micelle; EMULSION POLYMERIZATION; CONDUCTING POLYMERS; FABRICATION; EMERALDINE; NANOFIBERS; SALT;

D O I：

10.1080/25740881.2020.1738477

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We report a reverse-micelle emulsion polymerization of nanostructured PANI using a nonionic surfactant Polyglyceryl-2-Dipolyhydroxystearate (PGPH) at various concentrations from 2% to 6% (v/v). SEM images show that the obtained morphologies are irregular agglomerates at low PGPH concentration and relatively regular granules at high PGPH concentration. FTIR and Raman spectra show that the synthesized PANI is in the form of Emeraldine salt (PANI ES) with electrical conductivity around 10(-3) S cm(-1). Photovoltaic current-voltage (J-V) measurements show the highest power conversion efficiency is achieved at 1.71% at 6% (v/v) of PGPH.

引用

页码：1350 / 1358

页数：9

共 41 条

[1] Preparation of Polyaniline Emeraldine Salt for Conducting-Polymer-Activated Counter Electrode in Dye Sensitized Solar Cell (DSSC) using Rapid-Mixing Polymerization at Various Temperature
Amalina, Auliya N.
Suendo, Veinardi
Reza, Muhammad
Milana, Phutri
Sunarya, Risa R.
Adhika, Damar R.
Tanuwijaya, Viny V.
[J]. BULLETIN OF CHEMICAL REACTION ENGINEERING AND CATALYSIS, 2019, 14 (03) : 521 - 528
[2] Conducting polymers in microelectronics
Angelopoulos, M
[J]. IBM JOURNAL OF RESEARCH AND DEVELOPMENT, 2001, 45 (01) : 57 - 75
[3] Normal and reverse AOT micelles assisted interfacial polymerization for polyaniline nanostructures
Antony, M. Jinish
Jolly, C. Albin
Das, K. Rohini
Swathy, T. S.
[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2019, 578
[4] Synthesis of Spherical Nanostructured γ-Al2O3 Particles using Cetyltrimethylammonium Bromide (CTAB) Reverse Micelle Templating
Benu, Didi P.
Suendo, Veinardi
Mukti, Rino R.
Febriyanti, Erna
Steky, Fry, V
Adhika, Damar R.
Tanuwijaya, Viny V.
Nugraha, Ashari B.
[J]. BULLETIN OF CHEMICAL REACTION ENGINEERING AND CATALYSIS, 2019, 14 (03) : 542 - 550
[5] A low cost carbon black/polyaniline nanotube composite as efficient electro-catalyst for triiodide reduction in dye sensitized solar cells
Bora, Anindita
Mohan, Kiranjyoti
Phukan, Palash
Dolui, Swapan Kumar
[J]. ELECTROCHIMICA ACTA, 2018, 259 : 233 - 244
[6] Vibrational analysis of polyaniline: A model compound approach
Boyer, MI
Quillard, S
Rebourt, E
Louarn, G
Buisson, JP
Monkman, A
Lefrant, S
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (38): : 7382 - 7392
[7] Polyaniline for corrosion prevention of mild steel coupled with copper
Chen, Y.
Wang, X. H.
Li, J.
Lu, J. L.
Wang, F. S.
[J]. ELECTROCHIMICA ACTA, 2007, 52 (17) : 5392 - 5399
[8] Cochet M, 2000, J RAMAN SPECTROSC, V31, P1041, DOI 10.1002/1097-4555(200012)31:12<1041::AID-JRS641>3.0.CO
[9] 2-R
[10] Electronic interactions within composites of polyanilines formed under acidic and alkaline conditions. Conductivity, ESR, Raman, UV-vis and fluorescence studies
Dennany, L.
Innis, P. C.
McGovern, S. T.
Wallace, G. G.
Forster, Robert J.
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (08) : 3303 - 3310

← 1 2 3 4 5 →