Nano-MOF-5 (Zn) Derived Porous Carbon as Support Electrocatalyst for Hydrogen Evolution Reaction

被引：29
作者：
Nivetha, Ravi [1 ]
Gothandapani, Kannan [1 ]
Raghavan, Vimala [1 ]
Quyet Van Le [2 ]
Pitchaimuthu, Sudhagar [3 ]
Muthuramamoorty, Muthumareeswaran [4 ]
Pandiaraj, Saravanan [5 ]
Alodhayb, Abdullah [6 ]
Jeong, Soon Kwan [7 ]
Grace, Andrews Nirmala [1 ]
机构：
[1] Vellore Inst Technol, Ctr Nanotechnol Res, Vellore 632014, Tamil Nadu, India
[2] Duy Tan Univ, Inst Res & Dev, Da Nang 550000, Vietnam
[3] Heriot Watt Univ, Res Ctr Carbon Solut, Inst Mech Proc & Energy Engn, Sch Engn & Phys Sci, Edinburgh EH14 4AS, Midlothian, Scotland
[4] King Saud Univ, Coll Sci, POB 2455, Riyadh 11451, Saudi Arabia
[5] King Saud Univ, Dept Self Dev Skills, CFY Deanship, Riyadh 11451, Saudi Arabia
[6] King Saud Univ, Coll Sci, Dept Phys & Astron, POB 2455, Riyadh 11451, Saudi Arabia
[7] Korea Inst Energy Res, Climate Change Technol Res Div, Daejeon 305343, South Korea
来源：
CHEMCATCHEM | 2021年 / 13卷 / 20期
关键词：
Hydrogen evolution reaction; Fe; Pt; PC; Metal Organic Framework; Nano-MOF-5(Zn); Porous Carbon; METAL-ORGANIC FRAMEWORK; REDUCED GRAPHENE OXIDE; HIGH-PERFORMANCE; SURFACE-AREA; ELECTROCHEMICAL IMPEDANCE; OXIDATION; CATALYSTS; MOF-5; NANOCOMPOSITE; NANOPARTICLES;
D O I：
10.1002/cctc.202100958
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The design of an efficient electrocatalyst with controlled morphology and structural characteristics remain a challenging task for advanced electrochemical hydrogen evolution reaction (HER). Herein a simple method is utilized to improve the HER activity by introducing Fe/Pt bimetallic nanoparticles supported on highly porous carbon (PC) viz. one step carbonization of Nano-MOF-5(Zn) as precursor (metal organic framework). The as prepared Nano MOF-5(Zn), Fe/Pt-PC and PC derived from MOF were characterized by various techniques like X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, BET (nitrogen adsorption/desorption isotherms) and Field emission scanning electron microscopy (FE-SEM). The developed Fe-Pt/PC exhibits an optimal HER performance with low overpotential (85.4 mV) and a Tafel slope of 42.4 mV dec(-1). The electrochemical results show that the developed material provides a viable approach for developing inexpensive Pt-based catalyst for HER.
引用
收藏
页码：4342 / 4349
页数：8
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