Metal-Organic Frameworks with Incorporated Carbon Nanotubes: Improving Carbon Dioxide and Methane Storage Capacities by Lithium Doping

被引：265

作者：

Xiang, Zhonghua ^{[1
]}

Hu, Zan ^{[1
]}

Cao, Dapeng ^{[1
]}

Yang, Wantai ^{[2
]}

Lu, Jianmin ^{[2
]}

Han, Bingyong ^{[2
]}

Wang, Wenchuan ^{[1
]}

机构：

[1] Beijing Univ Chem Technol, Div Mol & Mat Simulat, Key Lab Nanomat, Minist Educ, Beijing 100029, Peoples R China

[2] Beijing Univ Chem Technol, Coll Mat Sci & Engn, Beijing 100029, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 02期

关键词：

adsorption; doping; gas storage; metal-organic frameworks; nanotubes; HYDROGEN STORAGE; H-2; STORAGE; CO2; ADSORPTION;

D O I：

10.1002/anie.201004537

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Permanent storage: The gas storage capacities of metal-organic frameworks can be increased by incorporation of carbon nanotubes and doping of the resulting framework with lithium ions (see picture, C-turquoise, Cu-green polyhedra, Li-purple, O-red). This combination of modifications results in an improvement of the CO2 and CH4 uptakes by about 305 % and 200 % (T=298-K and P=18-bar), respectively, compared to the unmodified compounds. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：491 / 494

页数：4

共 43 条

[41] Hydrogen Storage in Mesoporous Coordination Frameworks: Experiment and Molecular Simulation [J].

Xiang, Zhonghua ;

Lan, Jianhui ;

Cao, Dapeng ;

Shao, Xiaohong ;

Wang, Wenchuan ;

Broom, Darren P. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (34) :15106-15109

[42] Preparation and Enhanced Hydrostability and Hydrogen Storage Capacity of CNT@MOF-5 Hybrid Composite [J].

Yang, Seung Jae ;

Choi, Jae Yong ;

Chae, Hee K. ;

Cho, Jung Hyun ;

Nahm, Kee Suk ;

Park, Chong Rae .

CHEMISTRY OF MATERIALS, 2009, 21 (09) :1893-1897

[43]

Yang SH, 2009, NAT CHEM, V1, P487, DOI [10.1038/NCHEM.333, 10.1038/nchem.333]

← 1 2 3 4 5 →