Metal-Organic Frameworks with Incorporated Carbon Nanotubes: Improving Carbon Dioxide and Methane Storage Capacities by Lithium Doping

被引：265
作者：
Xiang, Zhonghua [1 ]
Hu, Zan [1 ]
Cao, Dapeng [1 ]
Yang, Wantai [2 ]
Lu, Jianmin [2 ]
Han, Bingyong [2 ]
Wang, Wenchuan [1 ]
机构：
[1] Beijing Univ Chem Technol, Div Mol & Mat Simulat, Key Lab Nanomat, Minist Educ, Beijing 100029, Peoples R China
[2] Beijing Univ Chem Technol, Coll Mat Sci & Engn, Beijing 100029, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 02期
关键词：
adsorption; doping; gas storage; metal-organic frameworks; nanotubes; HYDROGEN STORAGE; H-2; STORAGE; CO2; ADSORPTION;
D O I：
10.1002/anie.201004537
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Permanent storage: The gas storage capacities of metal-organic frameworks can be increased by incorporation of carbon nanotubes and doping of the resulting framework with lithium ions (see picture, C-turquoise, Cu-green polyhedra, Li-purple, O-red). This combination of modifications results in an improvement of the CO2 and CH4 uptakes by about 305 % and 200 % (T=298-K and P=18-bar), respectively, compared to the unmodified compounds. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：491 / 494
页数：4
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