Modeling of propane dehydrogenation combined with chemical looping combustion of hydrogen in a fixed bed reactor

被引：5

作者：

Liu, Junru ^{[1
]}

Hu, Rui ^{[1
]}

Liu, Xinlei ^{[1
]}

Zhang, Qunfeng ^{[1
]}

Ye, Guanghua ^{[1
]}

Sui, Zhijun ^{[1
]}

Zhou, Xinggui ^{[1
]}

机构：

[1] East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

来源：

CHINESE JOURNAL OF CHEMICAL ENGINEERING | 2022年 / 47卷

基金：

中国国家自然科学基金;

关键词：

Propane dehydrogenation; Selective hydrogen combustion; Simulation; Optimization; Redox process; CATALYTIC DEHYDROGENATION; OXYGEN CARRIERS; CARBON-DIOXIDE; H-2; PRODUCTION; METHANE; OXIDE; CERIA; OXIDATION; PARAFFINS;

D O I：

10.1016/j.cjche.2021.07.032

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A redox process combining propane dehydrogenation (PDH) with selective hydrogen combustion (SHC) is proposed, modeled, simulated, and optimized. In this process, PDH and SHC catalysts are physically mixed in a fixed-bed reactor, so that the two reactions proceed simultaneously. The redox process can be up to 177.0% higher in propylene yield than the conventional process where only PDH catalysts are packed in the reactor. The reason is twofold: firstly, SHC reaction consumes hydrogen and then shifts PDH reaction equilibrium towards propylene; secondly, SHC reaction provides much heat to drive the highly endothermic PDH reaction. Considering propylene yield, operating time, and other factors, the preferable operating conditions for the redox process are a feed temperature of 973 K, a feed pressure of 0.1 MPa, and a mole ratio of H-2 to C3H8 of 0.15, and the optimal mass fraction of PDH catalyst is 0.5. This work should provide some useful guidance for the development of redox processes for propane dehydrogenation. (C) 2021 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd. All rights reserved.

引用

页码：165 / 173

页数：9

共 40 条

[1] Mapping of the range of operational conditions for Cu-, Fe-, and Ni-based oxygen carriers in chemical-looping combustion [J].