Bi- and Tetranuclear Antimony(III) Bromide Complexes with Alkanediyl-bis(3-methylpyridinium) Cations

被引：3

作者：

Usol'tsev, A. N. ^{[1
]}

Sokolov, M. N. ^{[1
,2
]}

Fedin, V. P. ^{[1
]}

Adonin, S. A. ^{[1
,3
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

[2] Kazan Volga Reg Fed Univ, Butlerov Inst Chem, Kazan 420111, Russia

[3] South Ural State Univ, Chelyabinsk 454080, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2021年 / 66卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

antimony; halide complexes; polynuclear complexes; single crystal X-ray diffraction analysis; CRYSTAL-STRUCTURE; METHYLAMMONIUM LEAD; BISMUTH COMPLEXES; PHASE-TRANSITION; IODIDE; PEROVSKITE;

D O I：

10.1134/S003602362106019X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Polynuclear bromoantimonates(III) with alkanediyl-bis(3-methylpyridinium) cations (3-MePyCn2+)-(3-MePyC2)(3)[Sb2Br9](2) (1), (3-MePyC3)(2)[beta-Sb4Br16] (2), and (3-MePyC4)(2)[alpha-Sb4Br16] (3)-and bromobismuthate(III) (3-MePyC3)(3)[Bi2Br9](2) (4) have been synthesized by reacting solutions of Sb2O3 (Bi2O3) in HBr with bromides of the corresponding organic cations. Differences in the structure between compounds 1-3 and bromobismuthates with analogous cations (4 and previously studied compounds) have been considered.

引用

页码：827 / 833

页数：7

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