[2]Pseudorotaxanes through second-sphere coordination

被引：53
作者：
Blight, BA [1 ]
Van Noortwyk, KA [1 ]
Wisner, JA [1 ]
Jennings, MC [1 ]
机构：
[1] Univ Western Ontario, London, ON N6A 5B7, Canada
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 10期
关键词：
host-guest systems; hydrogen bonds; rotaxanes; self-assembly;
D O I：
10.1002/anie.200462380
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A macrocyclic tetralactam and simple trans-palladium dihalide complexes self-assemble to form [2]pseudorotaxanes. The pseudorotaxane superstructures are formed through second-sphere coordination of the metal ligands by the macrocyclic component (see picture; red: macrocycle with hydrogen atoms removed, blue: n-hexylamine, green: Cl, gray: Pd). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：1499 / 1504
页数：6
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