[2]Pseudorotaxanes through second-sphere coordination

被引：53

作者：

Blight, BA ^{[1
]}

Van Noortwyk, KA ^{[1
]}

Wisner, JA ^{[1
]}

Jennings, MC ^{[1
]}

机构：

[1] Univ Western Ontario, London, ON N6A 5B7, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 10期

关键词：

host-guest systems; hydrogen bonds; rotaxanes; self-assembly;

D O I：

10.1002/anie.200462380

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A macrocyclic tetralactam and simple trans-palladium dihalide complexes self-assemble to form [2]pseudorotaxanes. The pseudorotaxane superstructures are formed through second-sphere coordination of the metal ligands by the macrocyclic component (see picture; red: macrocycle with hydrogen atoms removed, blue: n-hexylamine, green: Cl, gray: Pd). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1499 / 1504

页数：6

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