Synthesis and properties of novel gemini surfactant with short spacer

被引:15
作者
Lu Ting [1 ]
Huang JianBin [1 ]
机构
[1] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
来源
CHINESE SCIENCE BULLETIN | 2007年 / 52卷 / 19期
基金
中国国家自然科学基金;
关键词
gemini surfactant; synthesis; elongated micelles;
D O I
10.1007/s11434-007-0398-3
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Cationic gemini surfactant dimethylene-1,2-bis(dodecyldiethylammonium bromide), referred to as C12C2C12(Et) was synthesized, and its surface property and aggregation behavior in aqueous solution were studied. The value of gamma at the critical micelle concentration (gamma (cmc)) is much smaller than that of the surfactant homologues with longer spacer. Spherical and elongated micelles were formed in the aqueous solution of this gemini surfactant, and the spherical micelles were absolutely dominant compared to the elongated micelles at our studied concentration quantitatively.
引用
收藏
页码:2618 / 2620
页数:3
相关论文
共 11 条
[1]   Sphere-to-cylinder transition in aqueous micellar solution of a dimeric (gemini) surfactant [J].
Bernheim-Groswasser, A ;
Zana, R ;
Talmon, Y .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (17) :4005-4009
[2]   ALKANEDIYL-ALPHA,OMEGA-BIS(DIMETHYLALKYLAMMONIUM BROMIDE) SURFACTANTS (DIMERIC SURFACTANTS) .5. AGGREGATION AND MICROSTRUCTURE IN AQUEOUS-SOLUTIONS [J].
DANINO, D ;
TALMON, Y ;
ZANA, R .
LANGMUIR, 1995, 11 (05) :1448-1456
[3]   Comparative studies on interactions of bovine serum albumin with cationic gemini and single-chain surfactants [J].
Li, YJ ;
Wang, XY ;
Wang, YL .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (16) :8499-8505
[4]   Aggregation properties of cationic gemini surfactants with partially fluorinated spacers in aqueous solution [J].
Li, YJ ;
Li, PX ;
Dong, CH ;
Wang, XY ;
Wang, YL ;
Yan, HK ;
Thomas, RK .
LANGMUIR, 2006, 22 (01) :42-45
[5]   Effect of hydrocarbon parts of the polar headgroup on surfactant aggregates in gemini and bola surfactant solutions [J].
Lu, Ting ;
Han, Feng ;
Mao, Guangru ;
Lin, Guofeng ;
Huang, Jianbin ;
Huang, Xu ;
Wang, Yilin ;
Fu, Honglan .
LANGMUIR, 2007, 23 (06) :2932-2936
[6]  
Menger FM, 2000, ANGEW CHEM INT EDIT, V39, P1907
[7]   GEMINI SURFACTANTS - SYNTHESIS AND PROPERTIES [J].
MENGER, FM ;
LITTAU, CA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (04) :1451-1452
[8]   Dimeric and oligomeric surfactants. Behavior at interfaces and in aqueous solution: a review [J].
Zana, R .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2002, 97 (1-3) :205-253
[9]   Dimeric (gemini) surfactants: Effect of the spacer group on the association behavior in aqueous solution [J].
Zana, R .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 248 (02) :203-220
[10]   ALKANEDIYL-ALPHA,OMEGA-BIS(DIMETHYLALKYLAMMONIUM BROMIDE) SURFACTANTS .1. EFFECT OF THE SPACER CHAIN-LENGTH ON THE CRITICAL MICELLE CONCENTRATION AND MICELLE IONIZATION DEGREE [J].
ZANA, R ;
BENRRAOU, M ;
RUEFF, R .
LANGMUIR, 1991, 7 (06) :1072-1075