Employing Cd-O-C rod-shaped secondary building units to construct 2D metal-organic frameworks (MOFs): hydrothermal synthesis, structures, and luminescent properties

被引：15

作者：

Luo, Feng ^{[1
]}

Che, Yun-Xia ^{[1
]}

Zheng, Ji-Min ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 13期

基金：

中国国家自然科学基金;

关键词：

hydrothermal synthesis; MOFs; SBUs; inorganic-organic rod structure;

D O I：

10.1080/00958970701870186

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Under hydrothermal conditions, in the presence of H(2)BDC, the self-assembly of CdCl(2), H(2)ip or H(2)NDC at pH = 7 generated two Cd(II)-containing coordination polymers, Cd(6)(ip)(6)(mu-H(2)O)(4) center dot H(2)O (1) and Cd(2)(NDC)(2)(mu-H(2)O)(2) (2) (H(2)BDC/H(2)ip/H(2)NDC = 1,4/1,3/1,2-benzenedicarboxylic acid). The structures are 2D metal-organic frameworks constructed from Cd-O-C rod-shaped SBUs (Secondary Building Units). Crystal samples in the solid state display strong fluorescence at 335 and 343 nm.

引用

页码：2097 / 2104

页数：8